Microwave Synthesis of Oxamide Ligands

Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (08): 1100-1102. Previous Articles Next Articles

Reports

草酰胺配体的微波合成

李选¹，陈晓影¹，袁荞龙*^,1，张丹枫¹，黄葆同¹,2

(¹华东理工大学材料科学与工程学院上海 200237)
(²中国科学院长春应用化学研究所长春 130022)

收稿日期:2005-08-03 修回日期:2006-02-08 发布日期:2006-07-26
通讯作者: 袁荞龙

Microwave Synthesis of Oxamide Ligands

LI Xuan¹,CHEN Xiao-Ying¹,YUAN Qiao-Long*^,1
ZHANG Dan-Feng¹,HUANG Bao-Tong¹,2

(¹ School of Materials Science and Engineering, East China University of Science and Technol-ogy, Shanghai 200237)
(² Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022)

Received:2005-08-03 Revised:2006-02-08 Published:2006-07-26
Contact: YUAN Qiao-Long

Abstract

N,N′-Bis(phenyl)oxamide and N,N′-bis(substituted phenyl)oxamides were synthesized from aniline, substituted anilines and oxalic acid under microwave irradiation in solvent-free. These compounds were identified by ¹H NMR, MS spectra and elemental analysis. The results showed that the product yield was increased by increase of irradiation power and option of appropriate irradiation time. The methyl or chloro substituted anilines were useful to increase the product yield than aniline, and the product yield was enhanced largely by increase of interface between solid and liquid.

Key words: oxalic acid, subsitituted aniline, N,N′-bis(substituted phenyl)oxamide, microwave irradiation

Cite this article

LI Xuan,CHEN Xiao-Ying,YUAN Qiao-Long*^,1
ZHANG Dan-Feng,HUANG Bao-Tong^1,2. Microwave Synthesis of Oxamide Ligands[J]. Chin. J. Org. Chem., 2006, 26(08): 1100-1102.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Xie Tinghui, Jiang Xiaoying, Mi Zhisheng, Li Xue, Xu Xiaohe, Bai Renren, Shuai Qi, Xie Yuanyuan. Iron/O₂-Promoted C-H Bond Functionalization for the Exclusive Synthesis of 2-Quinoline Carboxaldehydes under Microwave Irradiation [J]. Chinese Journal of Organic Chemistry, 2019, 39(11): 3294-3298.
[2]	Zong Chaoyang, Gu Huiwen, Zhang Lijie, Jin Yudong, Sun Yaquan. Microwave-Accelerated Dimroth Rearrangement for the Synthesis of Pyrido [2, 3-d]pyrimidin-4-amine Derivatives [J]. Chin. J. Org. Chem., 2018, 38(5): 1165-1171.
[3]	Qu Renyu, Chen Nian, Liu Yuchao, Chen Qiong, Yang Guangfu. An Efficient Synthesis of Functionalized 6-Arylsubstituted Salicylates via Microwave Irradiation [J]. Chin. J. Org. Chem., 2017, 37(5): 1266-1272.
[4]	Huang Yaobing, Yang Tao, Liu Anfeng, Zhou Xincheng, Pan Hui. Microwave-Assisted Alcoholysis of Cellulose to Methyl Levulinate Catalyzed by SnCl₄/H₂SO₄ [J]. Chin. J. Org. Chem., 2016, 36(6): 1438-1443.
[5]	Zhang Bianxiang, Yang Lihua, Shi Ruixue, Kang Yongqiang. Synthesis of Heterocyclic Aromatic Sulfides under Microwave Irradiation [J]. Chin. J. Org. Chem., 2016, 36(2): 352-357.
[6]	Zhang Rui, Pan Jinhuan, Wu Qiongyou. Copper Mediated One-Pot Multi-Component Synthesis of 3-Substitued Isoquinolines [J]. Chin. J. Org. Chem., 2016, 36(12): 2906-2911.
[7]	Zhu Jihua, Zheng Xudong, Guo Guozhe, Zhang Yuquan, Wu Bowan. Microwave-Assisted Synthesis of Asymmetrical 1,5-Disubstituted Carbonohydrazide and Crystal Structure [J]. Chin. J. Org. Chem., 2015, 35(9): 1975-1980.
[8]	Feng Junna, Li Xiaohui, Shao Jie, Zhu Mo, Li Yan, Chen Hua, Li Xiaoliu. Microwave Assisted Synthesis and Anti-HIV-RT Activity of Diaryl Benzo[1,3]thiazin-4-ones [J]. Chin. J. Org. Chem., 2015, 35(6): 1370-1374.
[9]	Wang Juxian, Lin Wei, Liu Hongtao, Hu Minghua, Feng Xian, Ren Jinfeng, Huang Zhibin, Shi Daqing. An Efficient Synthesis of Coumarino[4,3-d]pyrazolo[3,4-b]-pyridine Derivatives Catalyzed by Silica Sulfuric Acid under Microwave Irradiation [J]. Chin. J. Org. Chem., 2015, 35(4): 927-933.
[10]	Lu Hongyan, Shi Daxin, Zhang Qi, Yang Deli, Li Jiarong. Oxidation of Cucurbituril and Its Analogues [J]. Chin. J. Org. Chem., 2015, 35(2): 467-471.
[11]	Li Yingjun, Shi Xiangling, Gao Lixin, Jin Kun, Sheng Li, Wu Jianghong, Peng Lina, Li Jia. Synthesis, Characterization and Biological Activities of 3,5,6-Trisubstituted-1,2,4-triazine Derivatives [J]. Chin. J. Org. Chem., 2015, 35(1): 191-199.
[12]	Zhao Yunhui, Ren Xinfang, Liu Hanwen, Tang Zilong. Study on Synthesis of ortho-Hydroxyl Aromatic N-tert-Butylsulfinyl Imines under Microwave Irradiation [J]. Chin. J. Org. Chem., 2014, 34(6): 1218-1221.
[13]	Chen Hua, Huang Changjun, Zhu Mo, Li Xiaoliu. Synthesis and Anti-HIV-RT Activity of Novel Thiazolindin-4-one Derivatives Possessing Hydrophilic Groups [J]. Chin. J. Org. Chem., 2014, 34(4): 756-760.
[14]	Yang Jiaqiang, Ma Jun, Che Wanli, Li Minggang, Li Gang, Song Baoan. Microwave-Assisted Synthesis and Antitumor Activity of Salicyl Acyloxy Phosphonate Derivatives [J]. Chin. J. Org. Chem., 2014, 34(12): 2566-2571.
[15]	Tong Guangjin, Fan Wei, Jiang Bo. Three-Component Synthesis of Oxazolo[3,4-b]quinoline Derivatives [J]. Chin. J. Org. Chem., 2013, 33(12): 2578-2582.

草酰胺配体的微波合成

Microwave Synthesis of Oxamide Ligands

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments