Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (06): 703-723. Previous Articles     Next Articles

Review

Fe和Co催化的碳-碳偶联反应的最新进展

王晨,傅尧,刘磊,郭庆祥*   

  1. (Department of Chemistry, University of Science and Technology of China, Hefei 230026)
  • 收稿日期:2006-06-05 修回日期:2006-08-22 发布日期:2007-05-21
  • 通讯作者: 郭庆祥

New Advance of Fe- and Co-Catalyzed C-C Coupling Reactions

WANG Chen, FU Yao, LIU Lei, GUO Qing-Xiang*   

  • Received:2006-06-05 Revised:2006-08-22 Published:2007-05-21
  • Contact: GUO Qing-Xiang

As inexpensive and relatively nontoxic metals, Fe and Co are ideal elements for the development of catalysts. Because they have multiple redox states, Fe and Co are also anticipated to have very rich catalytic chemistry. Nonetheless, very little attention has been paid to the catalysis of Fe and Co. The present review surveys reaction conditions, yields and selectivity of the C-C coupling reactions. Possible mechanisms of these intriguing reactions are discussed. Applications of these new reactions to complex molecule synthesis are also described.

Key words: Co, green chemistry, C-C coupling reaction, catalysis, Fe