Catalytic Performance of Humic Acid Supported Pd/Ni Bimetallic Catalyst for Heck Reaction

Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (12): 1520-1524. Previous Articles Next Articles

Original Articles

腐植酸负载Pd/Ni双金属催化剂对Heck反应催化性能的研究

徐启杰^a，周大鹏^a，崔元臣*^,a,b

(^a河南大学化学化工学院开封 475001)
(^b河南大学天然产物与药物化学研究所开封 475001)

收稿日期:2006-12-05 修回日期:2007-04-05 发布日期:2007-12-04
通讯作者: 崔元臣

Catalytic Performance of Humic Acid Supported Pd/Ni Bimetallic Catalyst for Heck Reaction

XU Qi-Jie^a, ZHOU Da-Peng^a, CUI Yuan-Chen*^,a,b

(^aCollege of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001)
(^bResearch Institute of Natural Product and Pharmaceutical Chemistry, Henan Uni-versity, Kaifeng 475001)

Received:2006-12-05 Revised:2007-04-05 Published:2007-12-04
Contact: CUI Yuan-Chen

Abstract

The humic acid supported Pd/Ni bimetallic catalyst has been readily prepared, which can catalyze the Heck reaction of bromobenzene with acrylic acid or styrene in the yield above 85%. The catalyst can be reused to a certain extent. In the Heck reaction of bromobenzene with acrylic acid, the yield was 42.9% after the catalyst was reused for 3 times. While the yield was 26.7% after the catalyst was reused for 7 times in the Heck reaction of bromobenzene with styrene. And the catalyst can also catalyze the Heck reaction of substituted phenyl halide with acrylic acid or styrene.

Key words: bimetallic catalyst, Heck reaction, phenyl halide, humic acid

Cite this article

XU Qi-Jie^a, ZHOU Da-Peng^a, CUI Yuan-Chen*^{,a,b. Catalytic Performance of Humic Acid Supported Pd/Ni Bimetallic Catalyst for Heck Reaction[J]. Chin. J. Org. Chem., 2007, 27(12): 1520-1524.}

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腐植酸负载Pd/Ni双金属催化剂对Heck反应催化性能的研究

Catalytic Performance of Humic Acid Supported Pd/Ni Bimetallic Catalyst for Heck Reaction

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