Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (05): 761-767.     Next Articles

Review

铜催化碳-杂原子双键不对称硅氢加成反应的研究进展

陈玲珍,彭家建,厉嘉云,白赢,邱化玉*,来国桥*   

  1. (杭州师范大学有机硅化学及材料技术教育部重点实验室 杭州 310012)
  • 收稿日期:2007-07-09 修回日期:2007-09-07 发布日期:2008-05-20
  • 通讯作者: 邱化玉*,来国桥*

Progress in Asymmetric Hydrosilylation of Car-bon-HeteroatomUnsaturated Double Bond Compounds by Copper Catalyst

CHEN Ling-Zhen,PENG Jia-Jian,LI Jia-Yun,BAI Ying
QIU Hua-Yu*,LAI Guo-Qiao*   

  1. (Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education,
    Hangzhou Normal University, Hangzhou 310012)
  • Received:2007-07-09 Revised:2007-09-07 Published:2008-05-20
  • Contact: QIU Hua-Yu*,LAI Guo-Qiao*

The recent advances in asymmetric hydrosilylation of carbon-heteroatom unsaturated double bond compounds by copper catalysts were summarized. The performances of a variety of different substrates which were catalyzed by the combination of copper complexes and chiral ligand were analyzed. The possible mechanisms of asymmetric hydrosilylation were also discussed.

Key words: copper complex, asymmetric hydrosilylation, ketone, mechani