Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (11): 2007-2010. Previous Articles     Next Articles

Reports

硫(硒)杂多杯[4]芳烃合成及其络合性能研究

陈雪梅a,b ; 李海兵*,a   

  1. (a华中师范大学化学学院 农药与化学生物学教育部重点实验室 武汉 430079)
    (b黄石理工学院化学与材料工程学院 黄石 435003)
  • 收稿日期:2008-03-25 修回日期:2008-05-08 发布日期:2008-11-18
  • 通讯作者: 李海兵

Synthesis and Complexation Properties of Thia (Selena) Multi-calix[4]arene

CHEN, Xue-Mei a,b; LI, Hai-Bing*,a   

  1. (a Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry,
    Central China Normal University, Wuhan 430079)
    (b School of Chemical and Materials Engineering, Huangshi Institute of Technology, Huangshi 435003)
  • Received:2008-03-25 Revised:2008-05-08 Published:2008-11-18
  • Contact: LI, Hai-Bing

Thia (selena) calix[4]arenes were condensed with a calixarene segment, 2,6-bis (bromomethyl)- 4-methylanisole, to afford multi-calix[4]arenes 5a and 5b in presence of sodium hydride. The complexation abilities of the multi-calix[4]arenes with Ag+ and Hg2+ were superior to those of their monomers.

Key words: sulfur, calixarene, selenium, complexation, metalion