Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (12): 2149-2154. Previous Articles     Next Articles

Reports

高分子负载咪唑啉钯催化剂的合成及其对Heck反应的催化性能研究

林昆华*; 余喆吟 ; 钟燕华; 程知萱   

  1. (上海大学理学院化学系 上海 200444)
  • 收稿日期:2007-11-12 修回日期:2008-04-11 发布日期:2008-12-28
  • 通讯作者: 林昆华

Synthesis of Polymer(fiber)-Supported Palladium Catalyst Containing Imidazolinyl and Its Catalytic Performance to Heck Reaction

LIN, Kun-Hua* ;YU, Zhe-Yin; ZHONG, Yan-Hua; CHENG, Zhi-Xuan   

  • Received:2007-11-12 Revised:2008-04-11 Published:2008-12-28
  • Contact: LIN, Kun-Hua

Commercially available polyacrylonitrile (PAN) fiber was used as the polymer support material to synthesize a kind of polymer(fiber)-supported palladium catalyst. The structure of this catalyst was con-firmed by elemental analysis, FT-IR, atomic absorption spectrum, SEM and XPS. Its catalytic performance in Heck reaction of iodobenzene with ethyl acrylate was studied

Key words: Heck reaction, polymer(fiber), supported Pd cataly