Synthesis of MCM-41-Supported Thioether Palladium Complex and Its Catalytic Properties in Carbonylation of Aryl Halides

Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (2): 256-260. Previous Articles Next Articles

Original Articles

MCM-41负载硫醚钯配合物的合成及其催化芳基卤化物的羰基化性能

余腊妹^a，许秋华^b，蔡明中*^,a

(^a江西师范大学化学化工学院南昌 330022)
(^b南昌航空工业学院环境与化学工程学院南昌 330063)

收稿日期:2007-02-22 修回日期:2007-08-10 发布日期:2008-02-01
通讯作者: 蔡明中

Synthesis of MCM-41-Supported Thioether Palladium Complex and Its Catalytic Properties in Carbonylation of Aryl Halides

YU La-Mei^a,XU Qiu-Hua^b,CAI Ming-Zhong*^,a

(^a School of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022)
(^b School of Environmental and Chemical Engineering, Nanchang Institute of Aeronautical Technology, Nanchang 330063)

Received:2007-02-22 Revised:2007-08-10 Published:2008-02-01
Contact: CAI Ming-Zhong

Abstract

MCM-41-supported thioether palladium complex has been prepared via immobilization of 3-(2-cyanoethylsulfanyl)propyltriethoxysilane on MCM-41, followed by reacting with palladium chloride. The complex is an efficient catalyst for Heck carbonylation of aryl halides with aniline or n-butyl alcohol under atmospheric pressure of carbon monoxide. A variety of substituted N-phenylbenzamides and n-butyl benzoates were prepared. Importantly, the complex can be recovered and reused without loss of activity.

Key words: MCM-41, supported palladium catalyst, thioether palladium complex, aryl halide, carbonylation

Cite this article

YU La-Mei^a,XU Qiu-Hua^b,CAI Ming-Zhong*^,a. Synthesis of MCM-41-Supported Thioether Palladium Complex and Its Catalytic Properties in Carbonylation of Aryl Halides[J]. Chin. J. Org. Chem., 2008, 28(2): 256-260.

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MCM-41负载硫醚钯配合物的合成及其催化芳基卤化物的羰基化性能

Synthesis of MCM-41-Supported Thioether Palladium Complex and Its Catalytic Properties in Carbonylation of Aryl Halides

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