Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (04): 429-442.     Next Articles

Reviews

手性亚磷酰胺配体及其在不对称催化中的应用

张振锋,谢芳,杨波,余焓,张万斌*   

  1. (上海交通大学化学化工学院 上海 200240)
  • 收稿日期:2010-06-17 修回日期:2010-09-01 发布日期:2010-10-20
  • 通讯作者: 张万斌 E-mail:wanbin@sjtu.edu.cn

Chiral Phosphoramidite Ligand and Its Application in Asymmetric Catalysis

ZHANG Zhen-Feng, XIE Fang, YANG Bo, YU Han, ZHANG Wan-Bin   

  1. (School of Chemistry & Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240)
  • Received:2010-06-17 Revised:2010-09-01 Published:2010-10-20

Recent years, more and more chiral phosphoramidite ligands have been developed for a great number of asymmetric catalytic reactions because of their stable structure, facile synthesis, convenient modification and unique efficiency. This review describes the development of chiral phosphoramidite ligands and their applications in asymmetric catalysis, especially for enantioselective conjugate addition and allylic substitution.

Key words: phosphoramidite ligand, asymmetric catalysis, conjugate addition, allylic substitution