Synthesis and Structure Research of a Novel Tribond Bridged Bipyridine Complex

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (05): 757-761. Previous Articles Next Articles

Notes

一例新型桥联吡啶化合物的合成和结构研究

王鹏*^,1，赵静静¹，王忠卫²，曹德龙¹，徐建忠¹

(¹山东科技大学化学与环境工程学院青岛 266510)
(²山东科技大学材料科学与工程学院青岛 266510)

收稿日期:2010-09-28 修回日期:2010-11-17 发布日期:2010-12-28
通讯作者: 王鹏 E-mail:pengwang@sdust.edu.cn

Synthesis and Structure Research of a Novel Tribond Bridged Bipyridine Complex

Wang Peng*^,1 Zhao Jingjing¹ Wang Zhong-wei² Cao Delong¹ Xu Jianzhong¹

(¹College of Chemical and Environmental Engineering, Shandong University of Science and Tech-nology, Qingdao 266510)
(² College of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266510)

Received:2010-09-28 Revised:2010-11-17 Published:2010-12-28
Contact: Peng WANG E-mail:pengwang@sdust.edu.cn

A novel bipyridyl complex L [4-methyl-2,6-bis(pyridin-3-ylethynyl)aniline] was synthesized by an improved Sonogashira reaction through one-pot synthesis. Compared to common two-step synthesis method, the new route reduced reaction steps and improved the yield. The structure of L was characterized by IR, ¹H NMR and element analysis, and further confirmed by X-ray single crystal diffraction. Complex L crystallized in orthorhombic crystal system, Pca21 space group, with parameters of a＝10.178 Å, b＝10.972 Å, c＝28.949 Å|α＝β＝γ＝90°. L will be applied in coordination chemistry as a novel bent biprydyl ligand.

Key words: Sonogashira reaction, one-pot synthesis, X-ray single crystal diffraction, bipyriyl ligand

Cite this article

WANG Peng, ZHAO Jing-Jing, WANG Zhong-Wei, CAO De-Long, XU Jian-Zhong. Synthesis and Structure Research of a Novel Tribond Bridged Bipyridine Complex[J]. Chin. J. Org. Chem., 2011, 31(05): 757-761.

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一例新型桥联吡啶化合物的合成和结构研究

Synthesis and Structure Research of a Novel Tribond Bridged Bipyridine Complex

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