Chin. J. Org. Chem. ›› 2001, Vol. 21 ›› Issue (7): 505-513. Previous Articles     Next Articles

通过碳-碳键形成杂环的合成方法及应用

罗铁军;李正名   

  1. 南开大学元素有化学国家重点实验室;湖南省化工研究院.长沙
  • 发布日期:2001-07-25

Synthesis of hetereocycles by C---C bond-formation and its application

Luo Tiejun;Li Zhengming   

  1. Hunan Inst of Chem Ind.Changsha
  • Published:2001-07-25

This review includes five charged intemediate reactions for formation of heterocyclic ring by carbon-carbon bond (1) iminium ion- vinylsilane cyclizations, (2) nucleophile-promoted iminium ion-allyne cyclizations, (3) acetal-alkene cyclizations, (4) aza-Cope-Mannich reaction, and (5) synthesis of cyclic ethers by Prins-pinacol rearrangements and its application in organic (including natural products) synthesis.

Key words: HETEROCYCLIC COMPOUNDS, NATURAL PRODUCTS, TOTAL SYNTHESIS, SILANE P

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