Study of the reaction mechanisms of Ph~3P and (C~2H~5O)~3P with S~8 by MS and GC/MS

Chin. J. Org. Chem. ›› 1993, Vol. 13 ›› Issue (4): 377-382. Previous Articles Next Articles

Original Articles

亚磷酸三乙酯硫化反应历程的GC/MS研究

庞吉海;黄丽茹;吴国旺;戴敦华;朱国政

北京医科大学分析计算中心;北京药物化学研究所

发布日期:1993-08-25

Study of the reaction mechanisms of Ph~3P and (C~2H~5O)~3P with S~8 by MS and GC/MS

PANG JIHAI;HUANG LIRU;WU GUOWANG;DAI DUNHUA;ZHU GUOZHENG

Published:1993-08-25

Abstract

The reaction. mechanisms of Ph3P and (C2H5O)3P with S8 were studied by mass spectrometer and gas chromatograph-mass spectrometer. A previously reported (P. D. Bartlett et al., 1956) mechanism of the Ph3P-S8 reaction. was supported and a possible mechanism for the Ph3P-S8 and (C2H5O)3P-S8 reaction. is tested and verified.

Key words: REACTION MECHANISM, CHROMATOGRAPHY-MASS SPECTROGRAPHY, ETHYL GROUP, PHOSPHORUS ACID ESTERS, PHENYL GROUP

CLC Number:

O621.16

Cite this article

PANG JIHAI;HUANG LIRU;WU GUOWANG;DAI DUNHUA;ZHU GUOZHENG. Study of the reaction mechanisms of Ph~3P and (C~2H~5O)~3P with S~8 by MS and GC/MS[J]. Chin. J. Org. Chem., 1993, 13(4): 377-382.

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亚磷酸三乙酯硫化反应历程的GC/MS研究

Study of the reaction mechanisms of Ph~3P and (C~2H~5O)~3P with S~8 by MS and GC/MS

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