Condensation of Aromatic Aldehydes with 1,3-Cyclohexanedione Catalyzed by NaHSO4 in Ionic Liquids

Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (05): 640-642. Previous Articles Next Articles

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离子液体中NaHSO₄催化芳香醛与1,3-环己二酮的缩合反应

马晶军，李敬慈，唐然肖，周欣，吴秋华
王春*，张明明，李庆

(河北农业大学理学院保定 071001)

收稿日期:2006-04-26 修回日期:2006-09-23 发布日期:2007-05-10
通讯作者: 王春

Condensation of Aromatic Aldehydes with 1,3-Cyclohexanedione Catalyzed by NaHSO₄ in Ionic Liquids

MA Jing-Jun, LI Jing-Ci, TANG Ran-Xiao, ZHOU Xin, WU Qiu-Hua
WANG Chun*, ZHANG Ming-Ming, LI Qing

(College of Sciences, Agricultural University of Hebei, Baoding 071001)

Received:2006-04-26 Revised:2006-09-23 Published:2007-05-10
Contact: WANG Chun

Abstract

A series of 9-aryl-2,3,4,5,6,7-hexahydro-2H-xanthene-1,8-dione derivatives were synthesized from aromatic aldehydes and 1,3-cyclohexanedione derivatives catalyzed by NaHSO₄ in ionic liquids, 1-n-butyl-3-methylimidazolium tetrafluoroborate ([bmim]BF₄). The reactions were carried out in boiling water bath for 1～2 h, and the yield ranged from 1.2% to 93.0%. The catalyst employed is not expensive and the ionic liquid can be reusable. The proposed method is fast, efficient and environmentally friendly.

Key words: 9-aryl-2,3,4,5,6,7-hexahydro-2H-xanthene-1,8-dione, NaHSO₄, ionic liquid

Cite this article

MA Jing-Jun, LI Jing-Ci, TANG Ran-Xiao, ZHOU Xin, WU Qiu-Hua
WANG Chun*, ZHANG Ming-Ming, LI Qing. Condensation of Aromatic Aldehydes with 1,3-Cyclohexanedione Catalyzed by NaHSO₄ in Ionic Liquids[J]. Chin. J. Org. Chem., 2007, 27(05): 640-642.

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离子液体中NaHSO₄催化芳香醛与1,3-环己二酮的缩合反应

Condensation of Aromatic Aldehydes with 1,3-Cyclohexanedione Catalyzed by NaHSO₄ in Ionic Liquids

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离子液体中NaHSO4催化芳香醛与1,3-环己二酮的缩合反应