Studies on bis(crown ether)s IV: Formation of methylene bis(4'-benzo-15-crown-5)from the reaction of some N,N-aminodiacetic acids and benzo-15-crown-5 in PPA

Chin. J. Org. Chem. ›› 1989, Vol. 9 ›› Issue (2): 163-166. Previous Articles Next Articles

双冠醚的研究 IV: N,N-氨二乙酸类化合物与苯并-15-冠-5在多聚磷酸中生成亚甲基双(4'-苯并-15-冠-5)的反应

田宝芝;黄枢

四川大学化学系

发布日期:1989-04-25

Studies on bis(crown ether)s IV: Formation of methylene bis(4'-benzo-15-crown-5)from the reaction of some N,N-aminodiacetic acids and benzo-15-crown-5 in PPA

TIAN BAOZHI;HUANG SHU

Published:1989-04-25

Abstract

Formation of methylenebis(4'-benzo-15-crown-5) (I) has been accomplished by heating a mixture of benzo-15-crown-5 and N,N-aminodiacetic acid in polyphosphoric acid (PPA). The reaction pathway probably involves reaction of N,N-diacetic acids with PPA to form the corresponding anhydrides, followed by release of CO2 and CH2O thermally. As a result, I was formed by the condensation of CH2O with benzo-15-crown-5 under the action of PPA.

Key words: CROWN ETHER COMPOUNDS, BENZENE P, CYCLOHEXANE P, PHORSPHORIC ACID, EDTA, HIGHPOLYMER, METHYLATION, ACETIC ACID P, DIAMINE, IMINE, NITRILOTRIACETIC ACID

CLC Number:

O621

Cite this article

TIAN BAOZHI;HUANG SHU. Studies on bis(crown ether)s IV: Formation of methylene bis(4'-benzo-15-crown-5)from the reaction of some N,N-aminodiacetic acids and benzo-15-crown-5 in PPA[J]. Chin. J. Org. Chem., 1989, 9(2): 163-166.

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双冠醚的研究 IV: N,N-氨二乙酸类化合物与苯并-15-冠-5在多聚磷酸中生成亚甲基双(4'-苯并-15-冠-5)的反应

Studies on bis(crown ether)s IV: Formation of methylene bis(4'-benzo-15-crown-5)from the reaction of some N,N-aminodiacetic acids and benzo-15-crown-5 in PPA

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