Chin. J. Org. Chem. ›› 1991, Vol. 11 ›› Issue (4): 425-430. Previous Articles     Next Articles

Original Articles

甾酮类化合物的碱催化自氧化反应的研究

郭佳生;梁晓天   

  1. 中国医学科学院药物研究所
  • 发布日期:1991-08-25

Studies on Base-catalyzed autoxidation of steroid ketones

GUO JIASHENG;LIANG XIAOTIAN   

  • Published:1991-08-25

Passing oxygen into a solution of cyclocholestanone derivative I in THF-DMF containing NaOH at -25?gave 48% the hydroxy carboxylic acid II. (Cyclo)cholestan- and -enones III-VI were oxidized similarly.

Key words: STERONE, REACTION MECHANISM, CATALYTIC OXIDATION, AUTO-OXIDATION, BASE

CLC Number: