Palladium catalyzed allylation of active methylene compounds under PTC conditions

Chin. J. Org. Chem. ›› 1991, Vol. 11 ›› Issue (4): 431-433. Previous Articles Next Articles

Original Articles

钯催化下活性亚甲基化合物的烯丙基化相转移反应

吴国永;黄宪

浙江师范大学化学系;杭州大学化学系

发布日期:1991-08-25

Palladium catalyzed allylation of active methylene compounds under PTC conditions

WU GUOYONG;HUANG XIAN

Published:1991-08-25

Abstract

Allylation of di-Et malonate and 5-substituted Meldrum's acids with allyl chloride or allyl acetate occurred smoothly in the presence of dichlorobis(triphenylphosphine)palladium and under phase-transfer conditions.

Key words: TETRAHYDROFURAN, PHASE TRANSFER CATALYSIS, TRIPHENYLPHOSPHINE, DIETHYL ESTER, PALLADIUM, MALONIC ACID P, ALLYLATION

CLC Number:

O621

Cite this article

WU GUOYONG;HUANG XIAN. Palladium catalyzed allylation of active methylene compounds under PTC conditions[J]. Chin. J. Org. Chem., 1991, 11(4): 431-433.

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钯催化下活性亚甲基化合物的烯丙基化相转移反应

Palladium catalyzed allylation of active methylene compounds under PTC conditions

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