Synthesis, intramolecular cylization and nematocidity of O-polyhaloalkyl-O-substituted-phenyl-thiophosphoric hydrazides

Chin. J. Org. Chem. ›› 1997, Vol. 17 ›› Issue (4): 374-377. Previous Articles Next Articles

Original Articles

含O-多卤烷基-O-取代苯基硫逐磷酰肼的合成、分子内环化和杀虫活性

李盛彪;黄世强;何良年;黄天宝;周青春;王湘林

湖北大学化学系;华中师范大学有机合成研究所;湖北省电影公司

发布日期:1997-08-25

Synthesis, intramolecular cylization and nematocidity of O-polyhaloalkyl-O-substituted-phenyl-thiophosphoric hydrazides

HUANG SHIQIANG;HUANG TIANBAO;ZHOU QINGCHUN;WANG XIANGLIN

Published:1997-08-25

Abstract

Five new-O-polyhaloalkyl-O-substituted-phenyl- hydrazinophosphorates were synthesized and characterized by spectral data. In the presence of Et~3N, they are easily transferred into 1,3,4,2-oxadiazaphospholanes. The mechanism of the cylization of 1 to 2 was discussed. 1c and 2c showed a high activity against nematocides.

Key words: INSECTICIDAL ACTION, DIOXAZOLE P, PHOSPHOROUS HETEROCYCLIC COMPOUNDS, ORGANO PHOSPHORUS COMPOUNDS, HYDRAZIDE P, ORGANIC SYNTHESIS, CYCLOPENTANE P, CYCLIZATION, ORGANO SULFUR COMPOUNDS, REACTION MECHANISM

CLC Number:

O627

Cite this article

HUANG SHIQIANG;HUANG TIANBAO;ZHOU QINGCHUN;WANG XIANGLIN. Synthesis, intramolecular cylization and nematocidity of O-polyhaloalkyl-O-substituted-phenyl-thiophosphoric hydrazides[J]. Chin. J. Org. Chem., 1997, 17(4): 374-377.

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含O-多卤烷基-O-取代苯基硫逐磷酰肼的合成、分子内环化和杀虫活性

Synthesis, intramolecular cylization and nematocidity of O-polyhaloalkyl-O-substituted-phenyl-thiophosphoric hydrazides

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