Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (11): 1590-1593. Previous Articles     Next Articles

Reports

新型席夫碱大环化合物的合成

袁泽利,张奇龙,朱必学*   

  1. (贵州大学理学院化学系 贵阳 550025)
  • 收稿日期:2006-02-06 修回日期:1900-01-01 发布日期:2006-10-27
  • 通讯作者: 朱必学

Synthesis of New Schiff Base Macrocyclic Compounds

YUAN Ze-Li,ZHANG Qi-Long,ZHU Bi-Xue*   

  1. (Department of Chemistry, Guizhou University, Guiyang 550025)
  • Received:2006-02-06 Revised:1900-01-01 Published:2006-10-27
  • Contact: ZHU Bi-Xue

o-Phenylenediamine reacted with a series of α,ω-bis(3'-hydroxy-4'-formylphenyloxy) alkanes to yield new macrocyclic Schiff base compounds (Ln), using Mn2+ or Ba2+as a template. The complex compounds have been solved by Na2SO4 solution and become free ligands. The structures of new macrocyclic compounds were characterized by elemental analysis, UV-vis spectrophotometry, 1H NMR, IR and MS spectra.

Key words: template synthesis, Schiff base, macrocyclic compound, o-phenylenediamine