Peparation of iodine chloride supported on phosphonium resin and iodination  of active aromatic compounds

Chin. J. Org. Chem. ›› 2000, Vol. 20 ›› Issue (1): 98-101. Previous Articles Next Articles

载氯化碘Lin树脂的制备及其对活泼芳香化合物的碘化研究

杨桂春;陈祖兴;黄锦霞;陈家威

湖北大学化学与材料科学学院

发布日期:2000-02-25

Peparation of iodine chloride supported on phosphonium resin and iodination of active aromatic compounds

Yang Guichun;Chen Zuxing;Huang Jinxia;Chen Jiawei

Published:2000-02-25

Abstract

Phosphonium resin reacted with iodine chloride to give iodine chloride supported on phosphonim resin. The resin reacted with aromaticc amines、acetanilides and phenols in dichloromethane and methanol in the presence of calcium carbonate or sodium biscarbonate at room tempture to give mono iodo - substituted aromatic compounds. The yields were 80.5%～94.0%. The resin was a mild yet effective iodinating agent for active aromatic rings with good selectivity. The phosphonium resin can be reused after treatment with iodine chloride.

Key words: IODINE CHLORIDE, RESIN, IODINATION REACTION, AROMATIC AMINES

CLC Number:

TQ32

Cite this article

Yang Guichun;Chen Zuxing;Huang Jinxia;Chen Jiawei. Peparation of iodine chloride supported on phosphonium resin and iodination of active aromatic compounds[J]. Chin. J. Org. Chem., 2000, 20(1): 98-101.

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载氯化碘Lin树脂的制备及其对活泼芳香化合物的碘化研究

Peparation of iodine chloride supported on phosphonium resin and iodination of active aromatic compounds

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