Synthesis of 4,5-tetrathiafulvalene - bis (2,3,6,7- diphenyl -N- hetero - cycloheptane-1- oxyl)

Abstract

To developing high -Tc organic magnets based on aryl - substituted tetrathiafulvalene (TTF) donors with a multidimensional network of heteroatomic interactions, we have designed and synthesized of 4,5- tetrathiafulvalene-bis(2,3,4,7- diphenyl -N- hetero - cycloheptane -1- oxyl). The reaction products were isolated by preparative HPLC and identified by mass spectrometry, ^1H NMR and ^1^3C NMR.

Key words: FULVALENE (=BICYCLOPENTADIENYLI-DENE), NITROGEN HETEROCYCLICS, OXIDE, CYCLOHEPTANE P, MASS SPECTROGRAPHY, PROTON MAGNETIC RESONANCE SPECTROMETRY, C13 NMR SPECTROMETRY, MAGNETISM, ORGANO TIN COMPOUNDS

CLC Number:

O627

Cite this article

Zeng Heping. Synthesis of 4,5-tetrathiafulvalene - bis (2,3,6,7- diphenyl -N- hetero - cycloheptane-1- oxyl)[J]. Chin. J. Org. Chem., 2000, 20(1): 94-97.

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4,5-四硫富瓦烯-双(2,3,6,7-二苯基-氮杂环庚烷-1-氧化物)的合成