Chin. J. Org. Chem. ›› 2000, Vol. 20 ›› Issue (6): 905-909. Previous Articles     Next Articles

取代苯σ·Ⅱ效应分离与FMO能量的相关性 △E~X~.~σ~P^H^O研究

周文富   

  1. 福建三明高等专科学校化生工程系
  • 发布日期:2000-12-25

Quantative separation of σ·Ⅱ-electronic effect of substitued benzenes and correlation of △E~X~.~σ~P^H^O with FMO energy

Zhou Wenfu   

  • Published:2000-12-25

In this paper separation of inductive effect energy from conjugation effect energy is achieved. Quantitative explanation and application are discussed. the properties of (X)n group in ph(X)n in view of energy are proposed. it was found that all the substitents connected to the aromatic ring exibit σ~1 and σ~C effects to different extents and group orbit effect exist.

Key words: BENZENE, SUBSTITUENT EFFECT, CORRELATIONS, INDUCTIVE EFFECT

CLC Number: