Silver Fluoride-Promoted Intramolecular Cascade Reactions of Enynes

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (05): 653-658. Previous Articles Next Articles

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氟化银促进烯炔分子内串联反应研究

唐建生*^{,1,2，谢叶香²，王志强²，李金恒*^,2}

(¹湖南第一师范学院数理系长沙 410205)
(²湖南师范大学化学化工学院化学生物学与中药分析教育部重点实验室长沙 410081)

收稿日期:2010-07-27 修回日期:2010-11-15 发布日期:2010-12-09
通讯作者: 李金恒 E-mail:jhli@hunnu.edu.cn

Silver Fluoride-Promoted Intramolecular Cascade Reactions of Enynes

Tang Jiansheng*^{,1,2 Xie Yexiang² Wang Zhiqiang² Li Jinheng*^,2}

(¹ Mathematics and Science Department, Hunan First Normal University, Changsha 410205)
(² Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research (Ministry of Education), Hunan Normal University, Changsha 410081)

Received:2010-07-27 Revised:2010-11-15 Published:2010-12-09

Base-mediated intramolecular cascade reactions of enynes were carried out smoothly leading to arylnaphthalene lignan lactones. The results demonstrated that aryl-substituted enynes successfully underwent the intramolecular cascade reaction to afford the corresponding arylnaphthalene lignan lactones in moderate to excellent yields using AgF/K₂CO₃ mixture as the bases in CH₂ClCH₂Cl. It is noteworthy that silver fluoride can promote the intramolecular cascade reaction.

Key words: silver fluoride, enyne, cascade reaction, arylnaphthalene lignan lactone

Cite this article

TANG Jian-Sheng, XIE Ye-Xiang, WANG Zhi-Qiang, LI Jin-Heng. Silver Fluoride-Promoted Intramolecular Cascade Reactions of Enynes[J]. Chin. J. Org. Chem., 2011, 31(05): 653-658.

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氟化银促进烯炔分子内串联反应研究

Silver Fluoride-Promoted Intramolecular Cascade Reactions of Enynes

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