One-Pot Catalytic Synthesis of Amidoalkyl Naphthols Derivatives Under Solvent-Free Conditions

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (06): 870-873. Previous Articles Next Articles

Notes

无溶剂条件下“一锅法”催化合成胺基烷基萘酚衍生物

宋志国*^,1，赵爽²，万鑫²

(¹渤海大学科技实验中心锦州 121000)
(²渤海大学化学化工学院锦州 121000)c

收稿日期:2010-09-15 修回日期:2010-11-10 发布日期:2011-01-14
通讯作者: 宋志国 E-mail:szgbabylon@126.com

One-Pot Catalytic Synthesis of Amidoalkyl Naphthols Derivatives Under Solvent-Free Conditions

Song Zhiguo*^,1 Zhao Shuang² Wan Xin²

(¹ Center for Science & Technology Experiment, Bohai University, Jinzhou 121000)
(² College of Chemistry and Chemical Engineering, Bohai University, Jin-zhou 121000)

Received:2010-09-15 Revised:2010-11-10 Published:2011-01-14
Contact: Zhiguo Song E-mail:szgbabylon@126.com

Amidoalkyl naphthol derivatives were synthesized efficiently by a three components one-pot reaction of 2-naphthol, aldehydes and amines in the presence of copper o-toluenesulfonate without solvent. The effects of different solvent conditions and amount of catalysts on the yields were investigated. The result of catalyst circulation shows that its catalytic activity mostly remained after being reused four times. The structures of products were characterized by melting points, IR, ¹H NMR, ¹³C NMR, MS techniques and elemental analysis. In addition, the probable mechanism for the reaction was proposed.

Key words: amidoalkyl naphthol, copper o-toluenesulfonate, multicomponent reaction, solvent-free

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SONG Zhi-Guo, ZHAO Shuang, WAN Xin. One-Pot Catalytic Synthesis of Amidoalkyl Naphthols Derivatives Under Solvent-Free Conditions[J]. Chin. J. Org. Chem., 2011, 31(06): 870-873.

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无溶剂条件下“一锅法”催化合成胺基烷基萘酚衍生物

One-Pot Catalytic Synthesis of Amidoalkyl Naphthols Derivatives Under Solvent-Free Conditions

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