Progress in Synthesis and Application of Cyclosilazanes (1)— Cyclodisilazanes

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (06): 932-945. Previous Articles Next Articles

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环硅氮烷的合成与应用研究进展(1)——环二硅氮烷

滕雅娣*，孙驰宇，盛永刚，王淑丽

(沈阳化工大学应用化学学院沈阳 110142)

收稿日期:2010-10-27 修回日期:2010-12-31 发布日期:2011-01-14
通讯作者: 滕雅娣 E-mail:tengyadi@syict.edu.cn

Progress in Synthesis and Application of Cyclosilazanes (1)— Cyclodisilazanes

TENG Ya-Di, SUN Chi-Yu, SHENG Yong-Gang, WANG Shu-Li

(College of Applied Chemistry, Shenyang University of Chemical Technology, Shenyang 110142)

Received:2010-10-27 Revised:2010-12-31 Published:2011-01-14
Contact: TENG Ya-Di E-mail:tengyadi@syict.edu.cn

Abstract

Cyclodisilazanes are of great importance for their special configuration and property in organosilicon compounds. It has a significant and potential prospect of application in materials chemistry and coordination chemistry. The advances in synthesis and application on cyclodisilazanes in recent years are re-viewed. Three methods of synthesis which made from lithiated cyclotrisilizane, aminosilane and disilicon hexachloride are described. In application five reactions are shown, then the productions of cyclodisilazanes received by ion ring-opening polymerization, plasma polymerization, copolymerization, hydrolysis and metal coordination are used for manufacturing ceramic, adhesives and expected catalysts.

Key words: cyclodisilazanes, ion ring-opening polymerization, metal complex, ceramic precursor

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TENG Ya-Di, SUN Chi-Yu, SHENG Yong-Gang, WANG Shu-Li. Progress in Synthesis and Application of Cyclosilazanes (1)— Cyclodisilazanes[J]. Chin. J. Org. Chem., 2011, 31(06): 932-945.

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环硅氮烷的合成与应用研究进展(1)——环二硅氮烷

Progress in Synthesis and Application of Cyclosilazanes (1)— Cyclodisilazanes

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