Synthesis of 2,3-Dimethyl-2,3-dinitrobutane by Oxidative Coupling of Acetone Oxime

doi:10.6023/cjoc1107201

Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (04): 786-789.DOI: 10.6023/cjoc1107201 Previous Articles Next Articles

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丙酮肟氧化偶联合成2,3-二甲基-2,3-二硝基丁烷反应的研究

张胜建, 赵迎宪, 张洪

浙江大学宁波理工学院宁波 315100

收稿日期:2011-07-20 修回日期:2011-11-28 发布日期:2012-04-24
通讯作者: 张胜建 E-mail:zsj@nit.zju.edu.cn

Synthesis of 2,3-Dimethyl-2,3-dinitrobutane by Oxidative Coupling of Acetone Oxime

Zhang Shengjian, Zhao Yingxian, Zhang Hong

Ningbo Institute of Technology, Zhejiang University, Ningbo 315100

Received:2011-07-20 Revised:2011-11-28 Published:2012-04-24

2,3-Dimethyl-2,3-dinitrobutane (DMNB) was prepared by oxidative coupling of acetone oxime with H₂O₂ over the modified TS-1 catalyst. In one-pot operation, the ammoximation of acetone followed by catalytic oxidative coupling over TS-1 produced the DMNB with yield of 43.2%. The operation is simple and safe. The structures of products were identified by ¹H NMR and ¹³C NMR spectra.

Key words: acetone oxime, oxidative coupling, hydrogen peroxide, 2,3-dimethyl-2,3-dinitrobutane, modified TS-1 catalyst

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Zhang Shengjian, Zhao Yingxian, Zhang Hong. Synthesis of 2,3-Dimethyl-2,3-dinitrobutane by Oxidative Coupling of Acetone Oxime[J]. Chin. J. Org. Chem., 2012, 32(04): 786-789.

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丙酮肟氧化偶联合成2,3-二甲基-2,3-二硝基丁烷反应的研究

Synthesis of 2,3-Dimethyl-2,3-dinitrobutane by Oxidative Coupling of Acetone Oxime

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