A New Tetraphosphine and Its Application in Pd-Catalyzed Suzuki Cross-Coupling Reaction

doi:10.6023/cjoc1108181

Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (04): 790-793.DOI: 10.6023/cjoc1108181 Previous Articles Next Articles

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新型四齿膦配体在钯催化的Suzuki 偶联反应中的应用

张愚, 易韬, 王堃, 付海燕, 陈华, 李瑞祥

四川大学化学学院有机金属络合催化研究所绿色化学及技术教育部重点实验室成都 610064

收稿日期:2011-08-18 修回日期:2011-11-21 发布日期:2012-04-24
通讯作者: 李瑞祥 E-mail:liruixiang@scu.edu.cn

A New Tetraphosphine and Its Application in Pd-Catalyzed Suzuki Cross-Coupling Reaction

Zhang Yu, Yi Tao, Wang Kun, Fu Haiyan, Chen Hua, Li Ruixiang

Key Laboratory of Green Chemistry and Technology of the Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064

Received:2011-08-18 Revised:2011-11-21 Published:2012-04-24

A new tetraphosphine, N,N,N',N'-tetra(diphenylphosphinomethyl)-cyclohexane-1,2-diamine (1) has been designed and synthesized from the commercially available cyclohexane-1,2-diamine as starting material. This tetraphosphine in combination with [Pd(η³-C₃H₅)Cl]₂ is a very efficient catalyst for Suzuki cross-coupling reaction. Various aryl- and heteroaryl-chlorides as well as aryl-, heteroaryl-, and alkyl-bromides could be successfully transformed to the desired products in up to 99% yield with 0.1 mol% catalyst loading.

Key words: catalysis, palladium, tetraphosphine, Suzuki cross-coupling, phenylboronic acid

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Zhang Yu, Yi Tao, Wang Kun, Fu Haiyan, Chen Hua, Li Ruixiang. A New Tetraphosphine and Its Application in Pd-Catalyzed Suzuki Cross-Coupling Reaction[J]. Chin. J. Org. Chem., 2012, 32(04): 790-793.

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新型四齿膦配体在钯催化的Suzuki 偶联反应中的应用

A New Tetraphosphine and Its Application in Pd-Catalyzed Suzuki Cross-Coupling Reaction

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