Palladium-Catalyzed Suzuki Reaction in Aqueous Media

doi:10.6023/cjoc1109052

Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (05): 860-876.DOI: 10.6023/cjoc1109052 Previous Articles Next Articles

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水相钯催化Suzuki 反应

刘宁, 刘春, 金子林

大连理工大学精细化工国家重点实验室大连 116024

收稿日期:2011-09-05 修回日期:2011-11-04 发布日期:2011-12-09
通讯作者: 刘春 E-mail:cliu@dlut.edu.cn
基金资助:
国家自然科学基金(Nos. 20976024, 21076034)、大连理工大学离退休人员科研专项基金(No. DUTTX2011103)资助项目.

Palladium-Catalyzed Suzuki Reaction in Aqueous Media

Liu Ning, Liu Chun, Jin Zilin

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024

Received:2011-09-05 Revised:2011-11-04 Published:2011-12-09
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 20976024, 21076034) and the Special Research Foundation of Dalian University of Technology for Retired Professors (No. DUTTX 2011103).

The palladium-catalyzed Suzuki cross-coupling reaction has become one of the most powerful tools for sp²-sp² carbon-carbon bond formation. This coupling reaction is increasingly being applied in the synthesis of pharmaceuticals, natural products and advanced functional materials. In recent years, developing aqueous systems for the Suzuki reaction has attracted attention from many researchers. This paper reviews the recent progress in the Suzuki reaction using neat water and aqueous-organic co-solvent as reaction media. A large number of different strategies for the Suzuki reaction in water have been developed, in which the authors aim at the solutions to the enhancement of the reactivity of the palladium-catalyzed Suzuki reaction using water-soluble ligands, surfactants, microwave assistance, or ligand-free system.

Key words: Suzuki reaction, palladium catalyst, aqueous phase

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Liu Ning, Liu Chun, Jin Zilin. Palladium-Catalyzed Suzuki Reaction in Aqueous Media[J]. Chin. J. Org. Chem., 2012, 32(05): 860-876.

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水相钯催化Suzuki 反应

Palladium-Catalyzed Suzuki Reaction in Aqueous Media

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