One Pot Synthesis of Multiaryl Imidazoles Catalyzed by Modified Active Carbon Surported FeCl3

doi:10.6023/cjoc201406045

Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (12): 2511-2516.DOI: 10.6023/cjoc201406045 Previous Articles Next Articles

ARTICLE

改性活性炭负载FeCl₃催化一锅法合成多芳基咪唑

肖立伟, 高红杰, 孔洁, 刘光仙, 李玲玲, 段敬丹

廊坊师范学院化学与材料科学学院廊坊 065000

收稿日期:2014-06-26 修回日期:2014-08-08 发布日期:2014-08-28
通讯作者: 肖立伟 E-mail:xiaoliwei2000@sina.com
基金资助:
河北省自然科学基金(No.B2013408014)和廊坊师范学院重点(No.LSLZ201402)资助项目.

One Pot Synthesis of Multiaryl Imidazoles Catalyzed by Modified Active Carbon Surported FeCl₃

Xiao Liwei, Gao Hongjie, Kong Jie, Liu Guangxian, Li Lingling, Duan Jingdan

Faculty of Chemistry and Material Science, Langfang Teachers College, Langfang 065000

Received:2014-06-26 Revised:2014-08-08 Published:2014-08-28
Supported by:
Project supported by the Natural Science Foundation of Hebei Province (No. B2013408014) and the Key Foundation of Langfang Teachers University (No. LSLZ201402).

1. One Pot Synthesis of Multiaryl Imidazoles Catalyzed by Modified Active Carbon Surported FeCl₃.PDF(664KB)

Abstract

A novel modified active carbon surported ferric chloride catalyst (MAC-FeCl₃) has been developed, which has been characterized by IR and ICP. MAC-FeCl₃ exhibited excellent catalytic activities for one-pot synthesis of 2,4,5-triaryl imidazoles and 1,2,4,5-tetraaryl imidazoles from ammonium acetate, benzil, aromatic aldehydes or primary amines. The catalyst could be recycled easily and the activity of catalyst maintains stability after reused for 4 times, which makes this methodology has the advantages of good yields, less pollution and simple work-up.

Key words: modified active carbon surported FeCl₃, 2,4,5-triaryl imidazoles, 1,2,4,5-tetraaryl imidazoles, one-pot method, heterogeneous catalysis

Cite this article

Xiao Liwei, Gao Hongjie, Kong Jie, Liu Guangxian, Li Lingling, Duan Jingdan. One Pot Synthesis of Multiaryl Imidazoles Catalyzed by Modified Active Carbon Surported FeCl₃[J]. Chin. J. Org. Chem., 2014, 34(12): 2511-2516.

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改性活性炭负载FeCl₃催化一锅法合成多芳基咪唑

One Pot Synthesis of Multiaryl Imidazoles Catalyzed by Modified Active Carbon Surported FeCl₃

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改性活性炭负载FeCl3催化一锅法合成多芳基咪唑