Synthesis of Phosphine Ligands Based on 5-Amino-o-cresol and Its Application in Ethylene Oligomerization

doi:10.6023/cjoc201706010

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (3): 698-704.DOI: 10.6023/cjoc201706010 Previous Articles Next Articles

Notes

基于5-氨基邻甲酚的膦配体的合成及在乙烯齐聚中的应用

封智超^a, 毛国梁^a, 吴韦^a, 罗明检^a, 刘扬^b

a 东北石油大学化学化工学院石油与天然气化工省重点实验室大庆 163318;
b 东北石油大学石油工程学院大庆 163318

收稿日期:2017-06-09 修回日期:2017-07-28 发布日期:2017-11-28
通讯作者: 毛国梁,E-mail:maoguoliang@nepu.edu.cn E-mail:maoguoliang@nepu.edu.cn
基金资助:
国家自然科学基金（Nos.51534004，U1362110）和教育部新世纪优秀人才支持计划（No.NCET-07-0142）资助项目.

Synthesis of Phosphine Ligands Based on 5-Amino-o-cresol and Its Application in Ethylene Oligomerization

Feng Zhichao^a, Mao Guoliang^a, Wu Wei^a, Luo Mingjian^a, Liu Yang^b

a Provincial Key Laboratory of Oil & Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318;
b School of Petroleum Engineering, NortheastPetroleum University, Daqing 163318

Received:2017-06-09 Revised:2017-07-28 Published:2017-11-28
Contact: 10.6023/cjoc201706010 E-mail:maoguoliang@nepu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 51534004, U1362110), and the Program for New Century Excellent Talents in University (No. NCET-07-0142).

1. Synthesis of Phosphine Ligands Based on 5-Amino-o-cresol and Its Application in Ethylene Oligomerization.PDF(4080KB)

Abstract

A phosphorus ligand containing PNP and P-O structure was synthesized by substitution reaction of 5-amino-o-cresol with chlorodiphenylphosphine and its structure was conformed. Its in situ prepared complex with Cr(acac)₃ and preformed complex with CrCl₃(THF)₃ were used as main catalysts in catalyzing ethylene oligomerization, accompanied with methylaluminoxane (MAO) as cocatalyst. The effects of solvent, temperature, pressure and Al/Cr molar ratio on the activity and selectivity of the catalyst were investigated and compared with the in situ formation of 2-aminophenol and 4-aminophenol phosphine ligands catalytic system of catalyzing ethylene oligomerization effect. The experimental results showed that the activity reached 5.91×10⁶ g/(mol·Cr·h), when the reaction was carried at 50℃ with reaction pressure of 2.5 MPa and the Al/Cr molar ratio of 700. The selectivity of 1-octene was 72.94% and the total selectivity of 1-hexene and 1-octene was 82.11%.

Key words: 5-amino-o-cresol, phosphorus ligand, chromium catalyst, ethylene oligomerization, activity, selectivity

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Feng Zhichao, Mao Guoliang, Wu Wei, Luo Mingjian, Liu Yang. Synthesis of Phosphine Ligands Based on 5-Amino-o-cresol and Its Application in Ethylene Oligomerization[J]. Chin. J. Org. Chem., 2018, 38(3): 698-704.

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基于5-氨基邻甲酚的膦配体的合成及在乙烯齐聚中的应用

Synthesis of Phosphine Ligands Based on 5-Amino-o-cresol and Its Application in Ethylene Oligomerization

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