MCM-41 Immobilized H3PW12O40 Catalyzed the Addition-Elimination Reaction of Imine with Malonitrile in Water

doi:10.6023/cjoc201802006

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (7): 1749-1754.DOI: 10.6023/cjoc201802006 Previous Articles Next Articles

Articles

MCM-41负载杂多酸水相中催化亚胺和丙二腈的加成-消去反应

侯亚东^a, 董秀芝^a, 杨超^a, 惠永海^a,b, 解正峰^a,c

a 新疆大学化学化工学院石油天然气精细化工教育部重点实验室乌鲁木齐 830046;
b 岭南师范学院化学化工学院湛江 524048;
c 西南石油大学化学化工学院成都 610500

收稿日期:2018-02-03 修回日期:2018-03-07 发布日期:2018-03-29
通讯作者: 杨超, 惠永海 E-mail:jerryyang1924@163.com;hyhai97@126.com
基金资助:
国家自然科学基金（Nos.21362036，51564045）资助项目.

MCM-41 Immobilized H₃PW₁₂O₄₀ Catalyzed the Addition-Elimination Reaction of Imine with Malonitrile in Water

Hou Yadong^a, Dong Xiuzhi^a, Yang Chao^a, Hui Yonghai^a,b, Xie Zhengfeng^a,c

a Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046;
b School of Chemistry and Chemistry Engineering, Lingnan Normal University, Zhanjiang 524048;
c School of Chemistry and Chemistry Engineering, Southwest Petroleum University, Chengdu 610500

Received:2018-02-03 Revised:2018-03-07 Published:2018-03-29
Contact: 10.6023/cjoc201802006 E-mail:jerryyang1924@163.com;hyhai97@126.com
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21362036, 51564045).

1. MCM-41 Immobilized H₃PW₁₂O₄₀ Catalyzed the Addition-Elimination Reaction of Imine with Malonitrile in Water.PDF(1034KB)

Abstract

A convenient and excellent yield procedure for the preparation of benzylidenemalononitrile by addition-elimination reaction of imine with malonitrile in the presence of immobilized H₃PW₁₂O₄₀ as heterogeneous catalyst in water is described, and a variety of the corresponding products were obtained in high yield (up to 99%). The approach was characterized by simple operation, environment friendly, excellent yields and the catalyst was found to exhibit better recyclability. It provides a new method for the carbon-carbon bond formation in organic synthesis.

Key words: MCM-41, phosphoric acid, addition-elimination reaction, heterogeneous catalyst

Cite this article

Hou Yadong, Dong Xiuzhi, Yang Chao, Hui Yonghai, Xie Zhengfeng. MCM-41 Immobilized H₃PW₁₂O₄₀ Catalyzed the Addition-Elimination Reaction of Imine with Malonitrile in Water[J]. Chin. J. Org. Chem., 2018, 38(7): 1749-1754.

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MCM-41负载杂多酸水相中催化亚胺和丙二腈的加成-消去反应

MCM-41 Immobilized H₃PW₁₂O₄₀ Catalyzed the Addition-Elimination Reaction of Imine with Malonitrile in Water

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