Efficient, Solvent-Free Aminolysis of Monoesters Catalyzed by Sodium

doi:10.6023/cjoc201808006

Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (3): 873-877.DOI: 10.6023/cjoc201808006 Previous Articles Next Articles

Notes

金属钠催化下一元酯的高效无溶剂胺化反应

沈涛^a, 欧阳博^a,b, 周少东^a, 钱超^a, 陈新志^a

a 浙江大学浙江省化工高效制造技术重点实验室杭州 310027;
b 浙江花园生物高科有限公司东阳 322121

收稿日期:2018-08-07 修回日期:2018-09-28 发布日期:2018-10-26
通讯作者: 钱超 E-mail:qianchao@zju.edu.cn
基金资助:
国家自然科学基金（No.21476194）和国家重点研发计划（No.2016YFB0301800）资助项目.

Efficient, Solvent-Free Aminolysis of Monoesters Catalyzed by Sodium

Shen Tao^a, Ouyang Bo^a,b, Zhou Shaodong^a, Qian Chao^a, Chen Xinzhi^a

a Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, Zhejiang University, Hangzhou 310027;
b Zhejiang Garden Biochemical High-Tech Co., LTD, Dongyang 322121

Received:2018-08-07 Revised:2018-09-28 Published:2018-10-26
Contact: 10.6023/cjoc201808006 E-mail:qianchao@zju.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21476194) and the National Key Research and Development Program of China (No. 2016YFB0301800).

1. Efficient, Solvent-Free Aminolysis of Monoesters Catalyzed by Sodium.PDF(712KB)

Abstract

An efficient, solvent-free procedure using sodium as catalyst for the aminolysis of monoesters is reported. A detailed comparison of catalysts between sodium and sodium amide was made. It was found that the fresh sodium amide by in-situ synthesis of sodium with ammonia was more active than the indirectly adding sodium amide. As compared to the previously reported approaches, the procedure given in this work is much faster and performed under mild conditions. Furthermore, this procedure is applied successfully for the aminolysis of other monoesters.

Key words: monoester, aminolysis, sodium, sodium amide

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Shen Tao, Ouyang Bo, Zhou Shaodong, Qian Chao, Chen Xinzhi. Efficient, Solvent-Free Aminolysis of Monoesters Catalyzed by Sodium[J]. Chin. J. Org. Chem., 2019, 39(3): 873-877.

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金属钠催化下一元酯的高效无溶剂胺化反应

Efficient, Solvent-Free Aminolysis of Monoesters Catalyzed by Sodium

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