Progress in Synthesis of Eight-Membered Cyclic Ethers

doi:10.6023/cjoc201903068

Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (8): 2148-2156.DOI: 10.6023/cjoc201903068 Previous Articles Next Articles

Special Issue: 陈茹玉先生诞辰100周年

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八元环醚化合物合成方法研究进展

程诚^a, 孙孝斌^a, 苗志伟^a,b

a 南开大学化学学院元素有机化学国家重点实验室天津 300071;
b 天津化学化工协同创新中心天津 300071

收稿日期:2019-03-28 修回日期:2019-04-29 发布日期:2019-05-15
通讯作者: 苗志伟 E-mail:miaozhiwei@nankai.edu.cn
基金资助:
国家重点研发计划（No.2016YFD0201200）和南开大学中央高校基本科研业务费专项资金（No.63191205）资助项目.

Progress in Synthesis of Eight-Membered Cyclic Ethers

Cheng Cheng^a, Sun Xiaobin^a, Miao Zhiwei^a,b

a Research Institute of Elemento-organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071;
b Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300071

Received:2019-03-28 Revised:2019-04-29 Published:2019-05-15
Contact: 10.6023/cjoc201903068 E-mail:miaozhiwei@nankai.edu.cn
Supported by:
Project supported by the National Key Research and Development Program of China (No. 2016YFD0201200) and the Fundamental Research Funds for the Central Universities, Nankai University (No. 63191205).

Eight membered cyclic ether compounds are common structural motifs in natural products and bioactive molecules. The efficient synthesis of eight membered ethers has attracted wide attention for organic chemists. Compared with five-to seven-membered cyclic ethers, the synthesis of eight membered cyclic ethers is more challenging. In this paper, the synthetic methods for eight membered cyclic ethers by transition metal catalysis, ring expansion, retro-Claisen rearrangement, ring-closing metathesis, intramolecular amide enol alkylation and organic catalyzed tandem cyclization are reviewed.

Key words: eight-membered cyclic ethers, synthesis method, asymmetric synthesis

Cite this article

Cheng Cheng, Sun Xiaobin, Miao Zhiwei. Progress in Synthesis of Eight-Membered Cyclic Ethers[J]. Chin. J. Org. Chem., 2019, 39(8): 2148-2156.

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八元环醚化合物合成方法研究进展

Progress in Synthesis of Eight-Membered Cyclic Ethers

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