Recent Advances in Transition Metal-O Weak Coordinated C(sp2)—H Direct Alkenylation Reaction

doi:10.6023/cjoc202001004

Abstract

Over the past decade, the C(sp²)-H functionalization has emerged as a powerful methodology due to its high efficiency, simplicity, and high atomic economy. Among them, weak coordination between transition metal and oxygen atom has become an important strategy for C(sp²)-H alkenylation of arenes. In this paper, the transition metal-catalyzed C(sp²)-H alkenylation of substrates containing hydroxy, aryl ether, aldehyde, carbonyl, carboxyl, amide, phosphoric acid and sulfonic acid and their derivatives groups is reviewed, and its future development trends are prospected.

Key words: C(sp²)-H functionalization, transition metal, alkenylation, weak coordination

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Yin Biao, Fu Manlin, Zhu Qing. Recent Advances in Transition Metal-O Weak Coordinated C(sp²)—H Direct Alkenylation Reaction[J]. Chinese Journal of Organic Chemistry, 2020, 40(6): 1461-1472.

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基于过渡金属-O弱配位的C(sp²)—H直接烯基化反应进展

Recent Advances in Transition Metal-O Weak Coordinated C(sp²)—H Direct Alkenylation Reaction

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基于过渡金属-O弱配位的C(sp2)—H直接烯基化反应进展