Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (1): 318-324.DOI: 10.6023/cjoc202007003 Previous Articles Next Articles
Article
收稿日期:
2020-07-01
修回日期:
2020-08-07
发布日期:
2020-08-31
通讯作者:
张武
作者简介:
基金资助:
Feng Qina, Lin Tanga, Fei Huanga, Xiaoyue Lia, Wu Zhanga,*()
Received:
2020-07-01
Revised:
2020-08-07
Published:
2020-08-31
Contact:
Wu Zhang
Supported by:
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Feng Qin, Lin Tang, Fei Huang, Xiaoyue Li, Wu Zhang. Copper-Catalyzed Three-Component Synthesis of Quinolines via
Oxidation and Aza-Diels-Alder Reaction[J]. Chinese Journal of Organic Chemistry, 2021, 41(1): 318-324.
Entry | Catalyst | Oxidant | Solvent | Yield b /% |
---|---|---|---|---|
1 | CuBr | K 2S 2O 8 | DMF | 37 |
2 | CuBr | K 2S 2O 8 | DMA | 23 |
3 | CuBr | K 2S 2O 8 | DMSO | 67 |
4 | CuBr | K 2S 2O 8 | NMP | nr |
5 | Cu(OAc) 2 | K 2S 2O 8 | DMSO | 34 |
6 | CuCl 2 | K 2S 2O 8 | DMSO | 38 |
7 | CuBr 2 | K 2S 2O 8 | DMSO | 41 |
8 | CuCl | K 2S 2O 8 | DMSO | 58 |
9 | CuI | K 2S 2O 8 | DMSO | 76 |
10 | — | K 2S 2O 8 | DMSO | Trace |
11 c | CuI | K 2S 2O 8 | DMSO | 69 |
12 d | CuI | K 2S 2O 8 | DMSO | 44 |
13 | CuI | TBHP | DMSO | nr |
14 | CuI | O 2 | DMSO | nr |
15 | CuI | (NH 4) 2S 2O 8 | DMSO | 36 |
16 | CuI | — | DMSO | nr |
17 e | CuI | K 2S 2O 8 | DMSO | 42 |
18 f | CuI | K 2S 2O 8 | DMSO | 63 |
19 g | CuI | K 2S 2O 8 | DMSO | 77 |
20 h | CuI | K 2S 2O 8 | DMSO | 83 |
21 i | CuI | K 2S 2O 8 | DMSO | <10 |
Entry | Catalyst | Oxidant | Solvent | Yield b /% |
---|---|---|---|---|
1 | CuBr | K 2S 2O 8 | DMF | 37 |
2 | CuBr | K 2S 2O 8 | DMA | 23 |
3 | CuBr | K 2S 2O 8 | DMSO | 67 |
4 | CuBr | K 2S 2O 8 | NMP | nr |
5 | Cu(OAc) 2 | K 2S 2O 8 | DMSO | 34 |
6 | CuCl 2 | K 2S 2O 8 | DMSO | 38 |
7 | CuBr 2 | K 2S 2O 8 | DMSO | 41 |
8 | CuCl | K 2S 2O 8 | DMSO | 58 |
9 | CuI | K 2S 2O 8 | DMSO | 76 |
10 | — | K 2S 2O 8 | DMSO | Trace |
11 c | CuI | K 2S 2O 8 | DMSO | 69 |
12 d | CuI | K 2S 2O 8 | DMSO | 44 |
13 | CuI | TBHP | DMSO | nr |
14 | CuI | O 2 | DMSO | nr |
15 | CuI | (NH 4) 2S 2O 8 | DMSO | 36 |
16 | CuI | — | DMSO | nr |
17 e | CuI | K 2S 2O 8 | DMSO | 42 |
18 f | CuI | K 2S 2O 8 | DMSO | 63 |
19 g | CuI | K 2S 2O 8 | DMSO | 77 |
20 h | CuI | K 2S 2O 8 | DMSO | 83 |
21 i | CuI | K 2S 2O 8 | DMSO | <10 |
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