Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (7): 2707-2714.DOI: 10.6023/cjoc202103029 Previous Articles Next Articles
Special Issue: 热点论文虚拟合集
ARTICLES
王凯凯a, 陈绍维b, 李亚军b, 李达谅a,*(), 鲍红丽b,*()
收稿日期:
2021-03-18
修回日期:
2021-04-15
发布日期:
2021-04-29
通讯作者:
李达谅, 鲍红丽
基金资助:
Kaikai Wanga, Shaowei Chenb, Yajun Lib, Daliang Lia(), Hongli Baob()
Received:
2021-03-18
Revised:
2021-04-15
Published:
2021-04-29
Contact:
Daliang Li, Hongli Bao
Supported by:
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Kaikai Wang, Shaowei Chen, Yajun Li, Daliang Li, Hongli Bao. Iron-Catalyzed Decarboxylative Heck-Type Alkylation of Conjugate 1,3-Dienes[J]. Chinese Journal of Organic Chemistry, 2021, 41(7): 2707-2714.
Entry | Catalyst | Solvent | Temp/℃ | Yieldb/% |
---|---|---|---|---|
1 | Fe(OTs)3 | THF | 80 | 40 (2∶1) |
2 | Mn(OAc)2 | THF | 80 | Trace |
3 | MnBr2 | THF | 80 | Trace |
4 | MnCl2•4H2O | THF | 80 | Trace |
5 | Ni(acac)2 | THF | 80 | Trace |
6 | CoBr2 | THF | 80 | Trace |
7 | CuBr | THF | 80 | 4 |
8 | Fe(acac)3 | THF | 80 | 4 |
9 | FeCl2 | THF | 80 | 10 |
10 | Fe(OTf)3 | THF | 80 | 67 (2∶1) |
11 | Fe(OTf)3 | THF | 60 | 65 (2∶1) |
12 | Fe(OTf)3 | THF | 70 | 60 (2∶1) |
13 | Fe(OTf)3 | THF | 90 | 63 (2∶1) |
14 | Fe(OTf)3 | THF | 100 | 64 (2∶1) |
15 | Fe(OTf)3 | THF | 80 | 74 (2∶1)c |
Entry | Catalyst | Solvent | Temp/℃ | Yieldb/% |
---|---|---|---|---|
1 | Fe(OTs)3 | THF | 80 | 40 (2∶1) |
2 | Mn(OAc)2 | THF | 80 | Trace |
3 | MnBr2 | THF | 80 | Trace |
4 | MnCl2•4H2O | THF | 80 | Trace |
5 | Ni(acac)2 | THF | 80 | Trace |
6 | CoBr2 | THF | 80 | Trace |
7 | CuBr | THF | 80 | 4 |
8 | Fe(acac)3 | THF | 80 | 4 |
9 | FeCl2 | THF | 80 | 10 |
10 | Fe(OTf)3 | THF | 80 | 67 (2∶1) |
11 | Fe(OTf)3 | THF | 60 | 65 (2∶1) |
12 | Fe(OTf)3 | THF | 70 | 60 (2∶1) |
13 | Fe(OTf)3 | THF | 90 | 63 (2∶1) |
14 | Fe(OTf)3 | THF | 100 | 64 (2∶1) |
15 | Fe(OTf)3 | THF | 80 | 74 (2∶1)c |
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