Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (11): 4180-4191.DOI: 10.6023/cjoc202105056 Previous Articles     Next Articles

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芳基、烷基磷酸混酯类化合物的合成方法研究进展

焦林郁*(), 于华, 宁资慧, 李卓   

  1. 西北大学化工学院 西安 710069
  • 收稿日期:2021-05-31 修回日期:2021-06-30 发布日期:2021-07-26
  • 通讯作者: 焦林郁
  • 基金资助:
    国家自然科学基金(21901150)

Research Progress in the Preparation of Aryl and Alkyl Mixed Phosphates

Linyu Jiao(), Hua Yu, Zihui Ning, Zhuo Li   

  1. School of Chemical Engineering, Northwest University, Xi'an 710069
  • Received:2021-05-31 Revised:2021-06-30 Published:2021-07-26
  • Contact: Linyu Jiao
  • Supported by:
    National Natural Science Foundation of China(21901150)

Aryl and alkyl mixed phosphates are very important phosphorus containing organic compounds, which are widely used in many fields, such as biology, medicine, pesticide, polymer, and material science. The unique physical, chemical, and biological properties of phosphorus-based motifs provide more possibilities for their structural modification, derivatization, and potential application. Therefore, the research on the preparation of these compounds has important theoretical and practical significance. In this paper, the research progress of the synthesis methodologies of aryl and alkyl mixed phosphate in the past few decades is reviewed. The application examples are listed. The experimental methods and development process of the conversion of various kinds of phosphorus containing reagents to target compounds are summarized. The characteristics, mechanism, and application of the reaction are discussed selectively as well. We hope that this review can provide a reference for the development of new preparation protocols of mixed phosphate, and provide some useful references for scholars, graduate students, and others in the related fields.

Key words: synthetic method, mixed phosphate, organic phosphorus compound