Chinese Journal of Organic Chemistry ›› 2022, Vol. 42 ›› Issue (6): 1820-1830.DOI: 10.6023/cjoc202201011 Previous Articles Next Articles
Special Issue: 有机氟化学虚拟合辑
ARTICLES
收稿日期:
2022-01-10
修回日期:
2022-01-29
发布日期:
2022-02-17
通讯作者:
黄焰根
基金资助:
Xinling Lia, Weidong Menga, Xiuhua Xub, Yan'gen Huanga()
Received:
2022-01-10
Revised:
2022-01-29
Published:
2022-02-17
Contact:
Yan'gen Huang
Supported by:
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Xinling Li, Weidong Meng, Xiuhua Xu, Yan'gen Huang. Visible Light Induced Arylfluoroalkylation of Activated Alkenes[J]. Chinese Journal of Organic Chemistry, 2022, 42(6): 1820-1830.
Entry | Catalyst | Base | Solvent | Time/h | Yield b/% |
---|---|---|---|---|---|
1 | fac-Ir(ppy)3 | Et3N | DMSO | 12 | 42 |
2 | fac-Ir(ppy)3 | TMEDA | DMSO | 12 | 49 |
3 | fac-Ir(ppy)3 | DBU | DMSO | 12 | 44 |
4 | fac-Ir(ppy)3 | Cs2CO3 | DMSO | 12 | 75 |
5 | fac-Ir(ppy)3 | NaHCO3 | DMSO | 12 | 42 |
6 | fac-Ir(ppy)3 | K2CO3 | DMSO | 12 | 83 |
7 | Ru(bpy)3Cl2 | K2CO3 | DMSO | 12 | 42 |
8 | Eosin Y | K2CO3 | DMSO | 12 | 49 |
9 | Ir(ppy)2(dtbbpy)PF6 | K2CO3 | DMSO | 12 | 32 |
10 | Ru(bpy)3(PF6)2 | K2CO3 | DMSO | 12 | 39 |
11 | fac-Ir(ppy)3 | K2CO3 | MeCN | 12 | NR |
12 | fac-Ir(ppy)3 | K2CO3 | THF | 12 | NR |
13 | fac-Ir(ppy)3 | K2CO3 | DCE | 12 | 15 |
14 | fac-Ir(ppy)3 | K2CO3 | Acetone | 12 | 35 |
15 | fac-Ir(ppy)3 | K2CO3 | DMF | 12 | 20 |
16 | fac-Ir(ppy)3 | K2CO3 | DMSO | 10 | 56 |
17 | fac-Ir(ppy)3 | K2CO3 | DMSO | 14 | 81 |
Entry | Catalyst | Base | Solvent | Time/h | Yield b/% |
---|---|---|---|---|---|
1 | fac-Ir(ppy)3 | Et3N | DMSO | 12 | 42 |
2 | fac-Ir(ppy)3 | TMEDA | DMSO | 12 | 49 |
3 | fac-Ir(ppy)3 | DBU | DMSO | 12 | 44 |
4 | fac-Ir(ppy)3 | Cs2CO3 | DMSO | 12 | 75 |
5 | fac-Ir(ppy)3 | NaHCO3 | DMSO | 12 | 42 |
6 | fac-Ir(ppy)3 | K2CO3 | DMSO | 12 | 83 |
7 | Ru(bpy)3Cl2 | K2CO3 | DMSO | 12 | 42 |
8 | Eosin Y | K2CO3 | DMSO | 12 | 49 |
9 | Ir(ppy)2(dtbbpy)PF6 | K2CO3 | DMSO | 12 | 32 |
10 | Ru(bpy)3(PF6)2 | K2CO3 | DMSO | 12 | 39 |
11 | fac-Ir(ppy)3 | K2CO3 | MeCN | 12 | NR |
12 | fac-Ir(ppy)3 | K2CO3 | THF | 12 | NR |
13 | fac-Ir(ppy)3 | K2CO3 | DCE | 12 | 15 |
14 | fac-Ir(ppy)3 | K2CO3 | Acetone | 12 | 35 |
15 | fac-Ir(ppy)3 | K2CO3 | DMF | 12 | 20 |
16 | fac-Ir(ppy)3 | K2CO3 | DMSO | 10 | 56 |
17 | fac-Ir(ppy)3 | K2CO3 | DMSO | 14 | 81 |
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