Palladium-Catalyzed Carbonylation of Acetylenes in  Supercritical Carbon Dioxide

Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (2): 169-172. Previous Articles Next Articles

超临界二氧化碳介质中钯催化炔烃羰基化反应

谢叶香^a, 李金恒^*,a, 尹笃林^a, 江焕峰^b

^a湖南师范大学化学化工学院精细催化合成研究所长沙 410081
^b中国科学院广州化学研究所广州 510650

收稿日期:2003-03-25 修回日期:2003-06-23 接受日期:2003-08-25 发布日期:2022-09-20
基金资助:
国家自然科学基金(No. 20202002)资助项目

Palladium-Catalyzed Carbonylation of Acetylenes in Supercritical Carbon Dioxide

XIE, Ye-Xiang^a, LI, Jin-Heng^*,a, YIN, Du-Lin^a, JIANG, Huan-Feng^b

^aInstitute of Fine Catalysis and Synthesis, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081
^bGuangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650

Received:2003-03-25 Revised:2003-06-23 Accepted:2003-08-25 Published:2022-09-20
Contact: * E-mail: jhli@mail.hunnu.edu.cn

Abstract

An improved method for the palladium-catalyzed carbonylation of terminal acetylenes using supercritical carbon dioxide as the reaction medium has beendeveloped. The amount of alcohol, the pressure of carbon dioxide, and the reaction temperature were found to affect the chemoselectivity of the palladium-catalyzedcarbonylation of terminal acetylenes in supercritical carbon dioxide, i.e.there is a competition between carbonylation and oxidative coupling of terminal acetylenes.

Key words: supercritical carbon dioxide, terminal acetylene, carbonylation, oxidation coupling reaction

Cite this article

XIE, Ye-Xiang, LI, Jin-Heng, YIN, Du-Lin, JIANG, Huan-Feng. Palladium-Catalyzed Carbonylation of Acetylenes in Supercritical Carbon Dioxide[J]. Chinese Journal of Organic Chemistry, 2004, 24(2): 169-172.

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超临界二氧化碳介质中钯催化炔烃羰基化反应

Palladium-Catalyzed Carbonylation of Acetylenes in Supercritical Carbon Dioxide

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