Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (9): 1064-1068. Previous Articles     Next Articles

含胆甾基的双取代哒嗪的合成和介晶性

熊俊如*, 向清祥, 张元勤   

  1. 乐山师范学院环境与生命科学系 乐山 614004
  • 收稿日期:2003-11-10 修回日期:2004-03-25 接受日期:2004-03-25 发布日期:2022-09-20
  • 基金资助:
    乐山师范学院科研基金(No. ZB0305)资助项目.

Synthesis and Mesomorphism of Disubstituted Pyridazines Containing Cholesteryl

XIONG Jun-Ru*, XIANG Qing-Xiang, ZHANG Yuan-Qin   

  1. Department of Environment and Life Science, Leshan Teacher's College, Leshan 614004
  • Received:2003-11-10 Revised:2004-03-25 Accepted:2004-03-25 Published:2022-09-20
  • Contact: * E-mail: junruxiong@vip.sina.com

Eight new 3,6-disubstituted pyridazines, which contain cholesteryl, two benzene rings, an ester function and an alkoxyl group of different length, have been synthesized and characterized. Their mesomorphism has been studied through differential scanning (DSC). The length ofthe terminal chain can affect the transition and clearing point temperatures ofthe compounds, but has little influence on the temperature range of mesomorphousphases, which depend on the length of the rigid core.

Key words: cholestryl, pyridazine derivative, cross-coupling reaction, mesomorphism