Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (5): 1808-1814.DOI: 10.6023/cjoc202301027 Previous Articles Next Articles
Special Issue: 有机硼化学专辑
ARTICLES
收稿日期:
2023-01-31
修回日期:
2023-03-12
发布日期:
2023-03-23
通讯作者:
王剑波
基金资助:
Zhicheng Bao, Muyao Li, Jianbo Wang()
Received:
2023-01-31
Revised:
2023-03-12
Published:
2023-03-23
Contact:
Jianbo Wang
Supported by:
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Zhicheng Bao, Muyao Li, Jianbo Wang. Copper-Catalyzed Cross-Coupling of Aryldiazoacetates with Bis[(pinacolato)boryl]methane[J]. Chinese Journal of Organic Chemistry, 2023, 43(5): 1808-1814.
Entry | [Cu] | Ligand | Base | Solvent | Yieldb/ % |
---|---|---|---|---|---|
1 | CuCl | Ligandc | LiOtBu | Toluene | 0 |
2 | CuCl | L1 | LiOtBu | Toluene | 24 |
3 | CuCl | L2~L5 | LiOtBu | Toluene | 0 |
4 | CuCl | L1 | Based | Toluene | 0 |
5 | CuCl | L1 | LiOtBu | THF | 0 |
6 | CuCl | L1 | LiOtBu | DCE | 0 |
7 | CuCl | L1 | LiOtBu | m-Xylene | 18 |
8 | CuCl | L1 | LiOtBu | Chlorobenzene | 14 |
9 | CuCl | L1 | LiOtBu | Trifluorotoluene | 8 |
10e | CuCl | L1 | LiOtBu | Toluene | 38 |
11f | CuCl | L1 | LiOtBu | Toluene | 52 |
12 | CuBr | L1 | LiOtBu | Toluene | 30 |
13 | CuI | L1 | LiOtBu | Toluene | 24 |
14 | CuTC | L1 | LiOtBu | Toluene | 38 |
15 | Cu(MeCN)4PF6 | L1 | LiOtBu | Toluene | 48 |
16 | CuCl2 | L1 | LiOtBu | Toluene | 48 |
17g | CuCl | L1 | LiOtBu | Toluene | 54 |
18h | CuCl | L1 | LiOtBu | Toluene | 74 |
Entry | [Cu] | Ligand | Base | Solvent | Yieldb/ % |
---|---|---|---|---|---|
1 | CuCl | Ligandc | LiOtBu | Toluene | 0 |
2 | CuCl | L1 | LiOtBu | Toluene | 24 |
3 | CuCl | L2~L5 | LiOtBu | Toluene | 0 |
4 | CuCl | L1 | Based | Toluene | 0 |
5 | CuCl | L1 | LiOtBu | THF | 0 |
6 | CuCl | L1 | LiOtBu | DCE | 0 |
7 | CuCl | L1 | LiOtBu | m-Xylene | 18 |
8 | CuCl | L1 | LiOtBu | Chlorobenzene | 14 |
9 | CuCl | L1 | LiOtBu | Trifluorotoluene | 8 |
10e | CuCl | L1 | LiOtBu | Toluene | 38 |
11f | CuCl | L1 | LiOtBu | Toluene | 52 |
12 | CuBr | L1 | LiOtBu | Toluene | 30 |
13 | CuI | L1 | LiOtBu | Toluene | 24 |
14 | CuTC | L1 | LiOtBu | Toluene | 38 |
15 | Cu(MeCN)4PF6 | L1 | LiOtBu | Toluene | 48 |
16 | CuCl2 | L1 | LiOtBu | Toluene | 48 |
17g | CuCl | L1 | LiOtBu | Toluene | 54 |
18h | CuCl | L1 | LiOtBu | Toluene | 74 |
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