Chinese Journal of Organic Chemistry ›› 2024, Vol. 44 ›› Issue (4): 1045-1068.DOI: 10.6023/cjoc202310003 Previous Articles     Next Articles

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一氧化碳参与的过渡金属催化的插羰环加成反应研究进展

李晨龙, 余志祥*()   

  1. 北京大学化学与分子工程学院 北京分子科学国家研究中心 生物有机与分子工程教育部重点实验室 北京 100871
  • 收稿日期:2023-10-05 修回日期:2023-11-28 发布日期:2023-12-08
  • 基金资助:
    国家自然科学基金(21933003)

Progress in Transition-Metal-Catalyzed Carbonylative Cycloadditions Using Carbon Monoxide

Chen-Long Li, Zhi-Xiang Yu()   

  1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871
  • Received:2023-10-05 Revised:2023-11-28 Published:2023-12-08
  • Contact: E-mail: yuzx@pku.edu.cn
  • Supported by:
    National Natural Science Foundation of China(21933003)

Transition-metal-catalyzed cycloadditions have been evolved as important and efficient methods to construct cyclic molecules. Among them, transition-metal-catalyzed cycloadditions using carbon monoxide (CO) gas as the 1C synthon provide their unique and powerful approaches to build various cyclic molecules within a carbonyl group, which either acts as an important functional group within the cycloadducts, or can be further elaborated to other functional groups. The tremendous advances in this field are introduced.

Key words: cyclic molecule, carbon monoxide (CO) gas, transition metal catalysis, carbonylation, cycloaddition