Advances in the Reactions of CO2 and Epoxides Catalyzed by Heterometallic Complexes

doi:10.6023/cjoc202405048

Abstract

As global warming is getting serious, the concept of sustainable development is attracting increasing interests, and the utilization of CO₂ as a renewable resource is receiving intensive study. In the presence of catalysts, CO₂ reacts with epoxides to produce cyclic carbonates and polycarbonates. Cyclic carbonates have found wide applications in fields of lithium-ion batteries, organic synthesis and fine chemical production. Polycarbonates are a type of biodegradable polymer material, and can be used as adhesives, food packaging and optical media, etc. The reaction with epoxides is thus one representative of CO₂ utilization. Recent studies report that mononuclear and polynuclear metal complexes could catalyze this reaction. Among these examples, heterometallic complexes have shown good activities, due to the synergistic effect between different metals. The synthesis of heterometallic complexes and their applications in catalyzing the reactions of CO₂ with epoxides over the past 20 years are reviewed, and the characteristics of various catalysts as well as possible reaction mechanisms are discussed.

Key words: CO₂, epoxide, cyclic carbonate, polycarbonate, heterometallic complex

Cite this article

Yanwei Wang, Weiwei Chen, Dan Yuan, Yong Zhang, Yingming Yao. Advances in the Reactions of CO₂ and Epoxides Catalyzed by Heterometallic Complexes[J]. Chinese Journal of Organic Chemistry, 2024, 44(10): 3063-3076.

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Fig. & Tab. 4

Scheme 1. Coupling mechanism of CO2 with epoxides

Figure 1. General formula of DMC catalyst

Scheme 2. A possible chain shuttling mechanism for the complex 7e-catalyzed copolymerization of CO2 with epoxides

Scheme 2. A possible mechanism for the complex 21a-cata- lyzed cycloaddition reaction of CO2 with epoxides

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杂核金属配合物催化CO₂和环氧烷反应的研究进展

Advances in the Reactions of CO₂ and Epoxides Catalyzed by Heterometallic Complexes

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杂核金属配合物催化CO2和环氧烷反应的研究进展