Advancing Single-atom Photocatalysis in Organic Synthesis

doi:10.6023/cjoc202407042

Chinese Journal of Organic Chemistry Previous Articles Next Articles

单原子光催化有机合成研究进展

吴利华^a,&, 杨建静^a,&, 闫克鲁^a, 许丽荣^a, 文江伟^a,*

^a山东省绿色天然产物与医药中间体重点实验室,曲阜师范大学化学与化工学院,曲阜 273165

收稿日期:2024-07-28 修回日期:2024-09-17
基金资助:
山东省自然科学基金(No. ZR2020QB130),曲阜师范大学人才启动基金(No. 6125, 6132).

Advancing Single-atom Photocatalysis in Organic Synthesis

Lihua Wu^a,&, Jianjing Yang^a,&, Kelu Yan^a, Lirong Xu^a, Jiangwei Wen^a,*

^aKey Laboratory of Green Natural Products and Pharmaceutical Intermediates in Colleges and Universities of Shandong Province, School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, 2763165, P. R. China

Received:2024-07-28 Revised:2024-09-17
Contact: * E-mail: wenjy@qfnu.edu.cn
About author:^&These authors contributed equally to this work.
Supported by:
Natural Science Foundation of Shandong Province (No. ZR2020QB130), and Foundation of Qufu Normal University (NO. 6132 and 6125).

The single atom photocatalyst exhibits a large surface area, exceptional catalytic activity, and selectivity, thereby enhancing reaction efficiency and minimizing the occurrence of side reactions. Its catalytic mechanism is easily comprehensible, rendering it uniquely promising for organic synthesis reactions. The single-atom photocatalysis, in addition to its excellent recyclability, represents a novel and environmentally friendly catalytic strategy that offers unique opportunities for organic photocatalytic synthesis chemistry. Although single-atom photocatalysis has received widespread attention in many fields, its application in organic synthesis research is still relatively rare and lacks a systematic summary. In order to enable readers to quickly understand the progress in this field, the present review provides a comprehensive overview of the applications of single atom photocatalysts in various organic synthesis reactions over the past decade, classified according to bond formation involving C-C and C-X (X = N, O, S, P, B, etc.). Moreover, this review also elucidates the application range and underlying mechanisms involved in these reactions, aiming to lay the foundation for the development of new single-atom photocatalytic organic synthesis methods.

Key words: Single atom, Photocatalysis, Organic synthesis

Cite this article

Lihua Wu, Jianjing Yang, Kelu Yan, Lirong Xu, Jiangwei Wen. Advancing Single-atom Photocatalysis in Organic Synthesis[J]. Chinese Journal of Organic Chemistry, doi: 10.6023/cjoc202407042.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Ding S., Hülsey M.J., Pérez-Ramírez J.; Yan N. Joule. 2019, 3(12): 2897-2929.
[2] Qiao B., Wang A., Yang X., Allard L.F., Jiang Z., Cui Y., Liu J., Li J., Zhang T., Nature Chem., 2011,3(8): 634-641.
[3] Chen Z.W., Chen L. X., Yang C. C., Jiang Q. J. Mater. Chem. A. 2019, 7(8): 3492-3515.
[4] Zhang N., Ye C., Yan H., Li L., He H., Wang D., Li Y., Nano Research. 2020, 13(12): 3165-3182.
[5] Xiang H., Feng W., Chen Y., Adv. Mater., 2020, 32(8): e1905994.
[6] Zhang Q., Guan J., Adv. Funct. Mater., 2020, 30(31), 2000768-200821 .
[7] Qi P., Wang J., Djitcheu X., He D., Liu H., Zhang Q., RSC Adv. 2021, 12(2): 1216-1227.
[8] Kwak M., Bok J., Lee B.H., Kim J., Seo Y., Kim S., Choi H., Ko W., Hooch Antink W., Lee C. W., Yim G. H., Seung H., Park C., Lee K. S., Kim D. H., Hyeon T., Yoo D., Chem. Sci., 2022, 13(29): 8536-8542.
[9] Niu F., Tu W., Lu X., Chi H., Zhu H., Zhu X., Wang L., Xiong Y., Yao Y., Zhou Y., Zou Z., ACS Catal. 2022, 12(8): 4481-4490.
[10] Wang L., Yu M., Wu C., Deng N., Wang C., Yao X., Adv. Synth. Catal., 2016, 358(16): 2631-2641.
[11] Nasir Baig R.B., Verma S., Nadagouda M. N., Varma R. S. Green Chem., 2016, 18(4): 1019-1022.
[12] Vijeta A., Casadevall C., Reisner E., Angew. Chem. Int. Ed. Engl., 2022, 61(24): e202203176.
[13] Zhao E., Chen L., Zhu Q., Chen Z., Wei Y., Zhang W., Dong L., Fang W., Chen Z., Chin. J. Chem., 2023, 41(23): 3281-3289.
[14] Zhao X., Deng C., Meng D., Ji H., Chen C., Song W., Zhao J., ACS Catal., 2020, 10(24): 15178-15185.
[15] Vijeta A., Casadevall C., Roy S., Reisner E. Angew. Chem. Int.Ed., 2021,60(15): 8494-8499.
[16] Ma J., Zhang F., Tan Y., Wang S., Chen H., Zheng L., Liu H., Li R., ACS Appl. Mater. Interfaces. 2022, 14(16): 18383-18392.
[17] Zhang F., Ma J., Tan Y., Yu G., Qin H., Zheng L., Liu H., Li R., ACS Catal., 2022, 12(10): 5827-5833.
[18] Wu W., Cui E., Zhang Y., Zhang C., Zhu F., Tung C.-H., Wang Y., ACS Catal., 2019, 9(7): 6335-6341.
[19] Sun J.L., Jiang H., Dixneuf P. H., Zhang M., J. Am. Chem. Soc., 2023, 145(31): 17329-17336.
[20] Kim S., Bok J., Lee B.H., Choi H., Seo Y., Kim J., Kim J., Ko W., Lee K. S., Cho S. P., Hyeon T., Yoo D., ACS Nano. 2023, 17(21): 21470-21479.
[21] Yang J., Sun Z., Yan K., Dong H., Dong H., Cui J., Gong X., Han S., Huang L., Wen J., Green Chem., 2021, 23(7): 2756-2762.
[22] Wen J., Yang X., Sun Z., Yang J., Han P., Liu Q., Dong H., Gu M., Huang L., Wang H., Green Chem., 2020, 22(1): 230-237.
[23] Cui E., Li H., Zhang C., Qiao D., Gawande M.B., Tung C.-H., Wang Y. Appl. Catal. B-Environ. 2021, 299, 120674-120683.
[24] Jiao Z.-F., Tian Y.-M., Guo X.-N., Radius U., Braunschweig H., Marder T. B., Guo X. -Y., J. Catal., 2021, 395: 258-265.
[25] Wang G., Liu Y., Zhang X., Zong X., Zhang X., Zheng K., Qu D., An L., Qi X., Sun Z., J. Am.Chem. Soc., 2024, 146(12): 8668-8676.
[26] Li W., Zheng X., Xu B.B., Yang Y., Zhang Y., Cai L., Wang Z. J., Yao Y. F., Nan B., Li L., Wang X. L., Feng X., Antonietti M., Chen Z., Angew. Chem.Int. Ed., 2024: e202320014.
[27] Wang X., Chen W., Zhang L., Yao T., Liu W., Lin Y., Ju H., Dong J., Zheng L., Yan W., Zheng X., Li Z., Wang X., Yang J., He D., Wang Y., Deng Z., Wu Y., Li Y., J. Am. Chem.Soc., 2017, 139(28): 9419-9422.
[28] Chu X., Qu Y., Zada A., Bai L., Li Z., Yang F., Zhao L., Zhang G., Sun X., Yang Z.D., Jing L. Adv. Sci. 2020, 7(16): 2001543.
[29] Shah A.P., Sharma A. S., Sharma V. S., Shimpi N. G., ACS Applied Nano Mater., 2019, 3(2): 1922-1933.
[30] Shiraishi Y., Takeda Y., Sugano Y., Ichikawa S., Tanaka S., Hirai T., Chem. Commun., 2011, 47(27): 7863-7865.

单原子光催化有机合成研究进展

Advancing Single-atom Photocatalysis in Organic Synthesis

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Qingbao Gong, Xiang Lü, Changjiang Yu, Wanwan Li, Quansheng Zhao, Lijuan Jiao, Erhong Hao. Aggregation-Induced Emission (AIE) Active Fluoroboronated Pyridylhydrazinyl Aldehyde Hydrozone Dyes: Synthesis, Crystal Structure and Optical Properties [J]. Chinese Journal of Organic Chemistry, 2024, 44(8): 2545-2553.
[2]	Wenya Li, Yu Wang, Jiangqi Chen, Dan Shi, Liang Zhang, Xiaochun Yu, Zheng-Jun Wang. Developments in Visible Light Catalyzed Asymmetric Minisci Reactions [J]. Chinese Journal of Organic Chemistry, 2024, 44(7): 2110-2123.
[3]	Lingyi Lu, Xiaodong Qiu. Recent Progress in Radical Involved Alkene Dialkylation [J]. Chinese Journal of Organic Chemistry, 2024, 44(6): 1701-1718.
[4]	Yiping Sun, Demao Chen, Ling He, Zuli Wang. Na₂S₂O₈ Mediated C—H Amination of Imidazo[1,2-α]pyridines with Heteroaromatic Amines under Metal-Free Conditions [J]. Chinese Journal of Organic Chemistry, 2024, 44(5): 1667-1674.
[5]	Duyi Shen, Linghui Li, Ge Jing, Yujia Liang, Xinhui Zhang, Peiwei Gong, Fanjun Zhang, Mianran Chao. Advances in Flavin-Inspired Photocatalytic Oxidations Involving Single Electron Transfer Process [J]. Chinese Journal of Organic Chemistry, 2024, 44(4): 1069-1093.
[6]	Zenghui Ye, Huaqing Liu, Fengzhi Zhang. Recent Advances in Organic Electrophotocatalytic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(3): 840-870.
[7]	Aman Hasil, Rui Chang, Juntao Ye. Recent Advances on C—H Functionalization via Oxidative Electrophotocatalysis [J]. Chinese Journal of Organic Chemistry, 2024, 44(3): 728-747.
[8]	Qinggang Mei, Qinghan Li. Recent Progress of Visible Light-Induced the Synthesis of C(3) (Hetero)arylthio Indole Compounds [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 398-408.
[9]	Luyao Li, Zhongwen He, Zhenguo Zhang, Zhenhua Jia, Teck-Peng Loh. Application of Triaryl Carbenium in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 421-437.
[10]	Yanshuo Zhu, Hongyan Wang, Penghua Shu, Ke'na Zhang, Qilin Wang. Recent Advances on Alkoxy Radicals-Mediated C(sp³)—H Bond Functionalization via 1,5-Hydrogen Atom Transfer [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 1-17.
[11]	Qianfan Zhao, Yongzheng Chen, Shiming Zhang. Application and Mechanism Study of Carbon-Based Metal-Free Catalysts in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 137-147.
[12]	Hongqiong Zhao, Miao Yu, Dongxue Song, Qi Jia, Yingjie Liu, Yubin Ji, Ying Xu. Progress on Decarboxylation and Hydroxylation of Carboxylic Acids [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 70-84.
[13]	Yukun Jin, Baoyi Ren, Fushun Liang. Visible Light-Mediated Selective C—F Bond Cleavage of Trifluoromethyl Groups and Its Application in Synthesizing gem-Difluoro-Containing Compounds [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 85-110.
[14]	Ran Zhou, Chunmei Yuan, Tao Zhang, Piao Mao, Yi Liu, Kaini Meng, Hui Xin, Wei Xue. Design, Synthesis and Bioactivity of Chalcone Derivative Containing Quinazolinone [J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3196-3209.
[15]	Yingjie Liu, Gangqing Shi, Ge Chou, Xin Zhang, Dongxue Song, Ning Chen, Miao Yu, Ying Xu. Progress of α-Position Functionalization of Ethers under Photo/Electrocatalysis [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2664-2681.