Nonheme Iron(III)-Monoamidate Complexes as Catalysts for Methylene-Selective Oxidation of Simple Alkanes

doi:10.6023/cjoc202504021

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Yadan Chen, Songgang Huang, Jie Chen, Bin Wang. Nonheme Iron(III)-Monoamidate Complexes as Catalysts for Methylene-Selective Oxidation of Simple Alkanes[J]. Chinese Journal of Organic Chemistry, 2025, 45(12): 4453-4462.

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Fig. & Tab. 6

References 19

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Entry	Deviation from standard conditions	Product yield^b/%		A/K^c
Entry	Deviation from standard conditions	1a	1k	A/K^c
1	None	58	4.2	14
2	C2 instead of C1	11	2.9	3.8
3	C3 instead of C1	22	5.0	4.4
4^d	TFE instead of HFIP	57	6.7	8.5
5^d	NFTB instead of HFIP	ND	ND	ND
6	CH₃CN instead of HFIP	36	7.0	5.1
7^d	HFIPMe instead of HFIP	ND	ND	ND
8	3.0 mol% C1	60	4.6	13
9	1.0 mol% C1	44	32	14
10^d	Fe(ClO₄)₃•xH₂O instead of C1	ND	ND	ND
11	3.0 equiv. of H₂O₂	50	3.6	14
12	0.15 equiv. of HOAc	50	4.8	10
13	Without HOAc	43	3.9	11

Entry	Deviation from standard conditions	Product yield^b/%		A/K^c
Entry	Deviation from standard conditions	1a	1k	A/K^c
1	None	58	4.2	14
2	C2 instead of C1	11	2.9	3.8
3	C3 instead of C1	22	5.0	4.4
4^d	TFE instead of HFIP	57	6.7	8.5
5^d	NFTB instead of HFIP	ND	ND	ND
6	CH₃CN instead of HFIP	36	7.0	5.1
7^d	HFIPMe instead of HFIP	ND	ND	ND
8	3.0 mol% C1	60	4.6	13
9	1.0 mol% C1	44	32	14
10^d	Fe(ClO₄)₃•xH₂O instead of C1	ND	ND	ND
11	3.0 equiv. of H₂O₂	50	3.6	14
12	0.15 equiv. of HOAc	50	4.8	10
13	Without HOAc	43	3.9	11

Entry	BDE_C—H^b/(kJ•mol⁻¹)	A/K^d
1	416	14
2	400	12
3	393	7.2
4	400	5.4
5	406	8.0
6	414	12
7	402	6.6
8	415	2.8
8	415
9	410	3.8
9	410
10	410	4.1
10	410
11	407	2.4
11	407	2.4

Entry	BDE_C—H^b/(kJ•mol⁻¹)	A/K^d
1	416	14
2	400	12
3	393	7.2
4	400	5.4
5	406	8.0
6	414	12
7	402	6.6
8	415	2.8
8	415
9	410	3.8
9	410
10	410	4.1
10	410
11	407	2.4
11	407	2.4

非血红素三价铁-单酰胺配合物催化简单烷烃亚甲基选择氧化

Nonheme Iron(III)-Monoamidate Complexes as Catalysts for Methylene-Selective Oxidation of Simple Alkanes

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References 19

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Entry	BDE_C—H^b/(kJ•mol⁻¹)	A/K^d
1	416	14
2	400	12
3	393	7.2
4	400	5.4
5	406	8.0
6	414	12
7	402	6.6
8	415	2.8
8	415
9	410	3.8
9	410
10	410	4.1
10	410
11	407	2.4
11	407	2.4

Entry	BDE_C—H^b/(kJ•mol⁻¹)	A/K^d
1	416	14
2	400	12
3	393	7.2
4	400	5.4
5	406	8.0
6	414	12
7	402	6.6
8	415	2.8
8	415
9	410	3.8
9	410
10	410	4.1
10	410
11	407	2.4
11	407	2.4

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Entry	BDE_C—H^b/(kJ•mol⁻¹)	A/K^d
1	416	14
2	400	12
3	393	7.2
4	400	5.4
5	406	8.0
6	414	12
7	402	6.6
8	415	2.8
8	415
9	410	3.8
9	410
10	410	4.1
10	410
11	407	2.4
11	407	2.4

Entry	BDE_C—H^b/(kJ•mol⁻¹)	A/K^d
1	416	14
2	400	12
3	393	7.2
4	400	5.4
5	406	8.0
6	414	12
7	402	6.6
8	415	2.8
8	415
9	410	3.8
9	410
10	410	4.1
10	410
11	407	2.4
11	407	2.4

Entry	BDE_C—H^b/(kJ•mol⁻¹)	A/K^d
1	416	14
2	400	12
3	393	7.2
4	400	5.4
5	406	8.0
6	414	12
7	402	6.6
8	415	2.8
8	415
9	410	3.8
9	410
10	410	4.1
10	410
11	407	2.4
11	407	2.4

Entry	BDE_C—H^b/(kJ•mol⁻¹)	A/K^d
1	416	14
2	400	12
3	393	7.2
4	400	5.4
5	406	8.0
6	414	12
7	402	6.6
8	415	2.8
8	415
9	410	3.8
9	410
10	410	4.1
10	410
11	407	2.4
11	407	2.4