Iron-Photocatalytic Decarboxylative Functionalization Based on Ligand-to-Metal Charge Transfer

doi:10.6023/cjoc202505025

Chinese Journal of Organic Chemistry ›› 2025, Vol. 45 ›› Issue (10): 3517-3533.DOI: 10.6023/cjoc202505025 Previous Articles Next Articles

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基于配体-金属电荷转移的铁催化光致脱羧官能团化反应

张晨晨^a, 丁清杰^a, 吕琪妍^b^,^c, 马春华^a^,^*(), 姜玉钦^a^,^*(), 於兵^b^,^*()

^a 河南师范大学化学化工学院河南新乡 453007
^b 郑州大学化学学院郑州 450001
^c 南京林业大学林木生物质低碳高效利用国家工程研究中心南京 210037

收稿日期:2025-05-22 修回日期:2025-06-28 发布日期:2025-08-18
基金资助:
国家自然科学基金(82003585); 国家自然科学基金(21971224); 河南省高校科技创新人才支持计划(24HASTIT069); 河南省研究生教育改革与质量提升工程项目(YJS2025AL106); 河南省科技攻关项目(242102230095); 河南省高校基础研究专项(23ZX009); 河南师范大学优秀科技创新团队(2022TD03)

Iron-Photocatalytic Decarboxylative Functionalization Based on Ligand-to-Metal Charge Transfer

Chenchen Zhang^a, Qingjie Ding^a, Qiyan Lv^b^,^c, Chunhua Ma^a^,^*(), Yuqin Jiang^a^,^*(), Bing Yu^b^,^*()

^a School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007
^b College of Chemistry, Zhengzhou University, Zhengzhou 450001
^c National Engineering Research Center of Low-Carbon Processing and Utilization of Forest Biomass, Nanjing Forestry University, Nanjing 210037

Received:2025-05-22 Revised:2025-06-28 Published:2025-08-18
Contact: *E-mail: 2016007@htu.edu.cn; jiangyuqin@htu.edu.cn; bingyu@zzu.edu.cn
Supported by:
National Natural Science Foundation of China(82003585); National Natural Science Foundation of China(21971224); Program for Science & Technology Innovation Talents in Universities of Henan Province(24HASTIT069); Postgraduate Education Reform and Quality Improvement Project of Henan Province(YJS2025AL106); Key Science and Technology Project of Henan Province(242102230095); Special Project for Fundamental Research in University of Henan Province(23ZX009); Technical Innovation Team of Henan Normal University(2022TD03)

Decarboxylation functionalization reactions of carboxylic acids via photocatalysis have garnered significant attention recently due to their operational simplicity and mild reaction conditions. Among these, photocatalytic decar- boxylation reactions based on transition metal complexes, particularly those involving ligand-to-metal charge transfer, represent an effective strategy. Due to the natural abundance and low toxicity of the iron element, photocatalytic decar- boxylation reactions involving iron complexes have gained huge attention. This review summarizes the recent advances in the field of light-induced iron-catalyzed decarboxylation functionalization reactions over the past two years, aiming to establish a foundation for the development of new methodologies.

Key words: carboxylic acid, decarboxylation, photocatalytic, iron, ligand-to-metal charge transfer, functionalization

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Chenchen Zhang, Qingjie Ding, Qiyan Lv, Chunhua Ma, Yuqin Jiang, Bing Yu. Iron-Photocatalytic Decarboxylative Functionalization Based on Ligand-to-Metal Charge Transfer[J]. Chinese Journal of Organic Chemistry, 2025, 45(10): 3517-3533.

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Fig. & Tab. 16

Scheme 1. Process of ligand-to-metal charge transfer (LMCT)

Scheme 2. Fundamental principles of LMCT reactions in iron(III) carboxylate complexes

Scheme 3. Molecular oxygen-mediated iron-photocatalyzed decarboxylative oxidation of carboxylic acids

Scheme 4. Iron-photocatalysis/TEMPO oxidation system for decarboxylation oxidation of carboxylic acids

Scheme 5. Iron-photocatalytic decarboxylative hydrogenation of carboxylic acids

Scheme 6. Hydrofluoroalkylation of olefins via iron-photocatalytic decarboxylation of carboxylic acids

Scheme 7. Iron-photocatalytic decarboxylative fluorination of carboxylic acids

Scheme 8. Iron-photocatalytic decarboxylative halogenation of carboxylic acids

Scheme 9. Iron-photocatalytic decarboxylative azidation of carboxylic acids

Scheme 10. Photo-driven iron-copper bimetallic catalysis in the decarboxylative amination of carboxylic acids

Scheme 11. Iron-photocatalytic decarboxylation/reductive amination of carboxylic acids

Scheme 12. Iron-photocatalytic decarboxylative alkenylation of carboxylic acids

Scheme 13. Iron-photocatalytic decarboxylative alkynylation of carboxylic acids

Scheme 14. Iron-photocatalytic decarboxylative benzoylation of carboxylic acids

Scheme 15. Iron-photocatalytic decarboxylative thiolation of carboxylic acids

Scheme 16. Iron-photocatalytic decarboxylative sulfonation of carboxylic acids

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基于配体-金属电荷转移的铁催化光致脱羧官能团化反应

Iron-Photocatalytic Decarboxylative Functionalization Based on Ligand-to-Metal Charge Transfer

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