化学学报 ›› 2000, Vol. 58 ›› Issue (10): 1196-1201. 上一篇    下一篇

研究论文

油酸钠/水/十六烷/三丙烯酸季戊四醇酯体系层状 液晶的聚合

郭荣;傅清红;张晓红   

  1. 扬州大学理学院化学系;中国人民解放军总后勤部重庆后勤工程学院
  • 发布日期:2000-10-15

Copolymerization of NaOL/hexadecane/PETA/H~2O lamellar liquid crystal system

Guo Rong;Fu Qinghong;Zhang Xiaohong   

  • Published:2000-10-15

将十六烷增溶于油酸钠(NaOL)/水体系层状液晶的油层,共聚单体三丙烯酸季戊四醇酯(PETA)增溶于油酸钠/水体系层状液晶的两亲双层。72℃下,以增容于油层中的十六烷作为阻隔。在层状液晶同一两新双层内的两新分子油酸钠与共聚单体PETA之间进行共聚,得到了具有层状结构、并具有较好表面活性的共聚物。

关键词: 油酸钠, 水, 十六烷, 三丙烯酸季戊四醇, 液晶, 聚合

hexadecane was solubilized in the oil layer, while PETA comononer in the amphiphile double layer in the NaOL/H~2O lamellar liquid crystal system. Using hexadecane as spacing, copolymerization took place between NaOL amphiphilic molecule and PETA comononer in each amphiphile bilayer of the lamellar liquid crystal phase, the polymer with lamellar structure and surface activity was obtained at 72℃.

Key words: SODIUM OLEATE, WATER, DIOCTYL, LIQUID CRYSTAL, POLYMERIZATION

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