SIOC English
化学学报
高级检索

化学学报 ›› 1990, Vol. 48 ›› Issue (2): 204-207. 上一篇    

研究论文

Schiff碱配合物的研究II: 一些Fe(III)配合物的磁性质与电化学行为

汪信;KOTUN, M.E.;FANNING, J.C   

  1. 华东工学院近代化学研究室;美国克莱姆森大学化学系
  • 发布日期:1990-02-15

Studies on schiff base complexes: II, magnetic and electrochemical behaviors of some iron (III)complexes

WANG XIN;KOTUN, M.E.;FANNING, J.C   

  • Published:1990-02-15

PDF

584

Fe(III)schiff碱配合物的磁性质和电化学还原性是该类配合物的基本特性, 本文研究三种配合物, 单核高自旋配合物, 单核低自旋配合物以及氧桥双核配合物的核磁共振性质电化学还原性。

关键词: 铁络合物, 核磁共振, 席夫碱, 磁性, 电化学

The magnetic and electrochem. properties of Fe(III) complexes Fe(salen)NO2, [Fe(salen)NO3]2, Fe(salen)(SCN), K[Fe(salen)(CN)2], [Fe(salen)]2O and [Fe(5-NO2 saldpt]2O, where salen = salicylidene-ethylenediamine and saldpt = salicylidene-propylenediamine, were studied. The NMR chem. shifts and the Moessbauer spectra parameters were determine experimental The oxidation- behavior was studied by cyclic voltammetry. The effects of m-oxo bridging on the structure and electrochem properties were studied.

Key words: IRON COMPLEX, NUCLEAR MAGNETIC RESONANCE, SCHIFF BASE, MAGNETISM, ELECTROCHEMISTRY

中图分类号: