化学学报 ›› 2011, Vol. 69 ›› Issue (10): 1259-1263. 上一篇    下一篇

研究论文

壳聚糖/氧化石墨烯纳米复合材料的形态和力学性能研究

赵茜1, 邱东方2, 王晓燕3, 刘天西*,3   

  1. (1南阳师范学院学报编辑部 南阳 473061)
    (2南阳师范学院化学与制药工程学院 南阳 473061)
    (2聚合物分子工程教育部重点实验室 复旦大学高分子科学系 上海 200433)
  • 投稿日期:2010-12-31 修回日期:2011-01-25 发布日期:2011-01-30
  • 通讯作者: 刘天西 E-mail:txliu@fudan.edu.cn

Morphology and Mechanical Properties of Chitosan/ Graphene Oxide Nanocomposites

Zhao Qian1,Qiu Dongfang2,Wang Xiaoyan3,Liu Tianxi*,3   

  1. (1 Journal Editorial Department of Nanyang Normal University,, Nanyang 447733006611) (2 Chemistry and Pharmaceutical Engineering College,, Nanyang Normal University,, Nanyang 447733006611) (3 Key Laboratory of Molecular Engineering of Polymers of Ministry of Education,, Department of Macromolecular Science,, Fudan University,, Shanghai 220000443333)
  • Received:2010-12-31 Revised:2011-01-25 Published:2011-01-30
  • Contact: Tianxi Liu E-mail:txliu@fudan.edu.cn

通过溶液共混法成功制备了氧化石墨烯/壳聚糖纳米复合材料. 透射电镜(TEM)结果表明, 氧化石墨烯纳米粒子在壳聚糖基体中分散良好. 拉伸实验结果表明, 随氧化石墨烯含量的增加, 氧化石墨烯/壳聚糖纳米复合材料的杨氏模量和拉伸强度均显著改善, 加入4 wt%的氧化石墨烯能够使纳米复合材料的杨氏模量和拉伸强度分别提高123%和117%|但另一方面, 却也在一定程度上使复合材料的断裂伸长率或韧性下降.

关键词: 石墨烯, 壳聚糖, 纳米复合材料

Chitosan/graphene oxide nanocomposites were prepared by solution blending method. TEM observations showed that the graphene oxide (GO) was well dispersed in chitosan matrix. By incorporating GO into chitosan, both tensile strength and modulus of the nanocomposites were significantly increased due to the fine dispersion of GO and strong interfacial interactions between GO and the chitosan matrix, while their elongation at break decreased to certain extent.

Key words: graphene, chitosan, nanocomposites