Acta Chimica Sinica ›› 2002, Vol. 60 ›› Issue (11): 1951-1956. Previous Articles     Next Articles

Original Articles

甘氨酸在葡萄糖-水和蔗糖-水混合溶剂中的体积性质

李淑芹;桑文强;林瑞森   

  1. 中国科学院植物研究所光合作用研究中心.北京(100093);浙江大学化学系杭 州(310027)
  • 发布日期:2002-11-15

Volumetric Properties of Glycine in Glucose-Water and Sucrose-Water Mixed Sovents at 298.15K

Li Shuqin;Sang Wenqiang;Lin Ruisen   

  1. Photosynthesis Center, Institute of Botany, Chinese Academy of Sciences.Beijing(100093);Department of Chemistry, Zhejiang University, Hangzhou(310027)
  • Published:2002-11-15

Densities of glycine in glucose-water and sucrose-water mixed solvents have been measured to 298.15 K by an oscillating-tube densimeter. Apparent molar volumes, limiting partial molar volumes and number of hydration of glycine have been calculated. The transfer volumes from water to sugar-water mixtures have been obtained and discussed in terms of the structural hydration interaction model. The results obtained have been compared with that in glycerol-water and ethylene glycol-water mixtures. It is concluded that the magnitude of enhancement effect on volume is related to the number of OH groups.

Key words: GLYCINE, GLUCOSE, SUCROSE, WATER, SOLVENTS, INTERACTIONS, VOLUME CHANGE

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