Acta Chimica Sinica ›› 2001, Vol. 59 ›› Issue (12): 2122-2125. Previous Articles     Next Articles

Original Articles

CTAB水溶液表面的吸附动力学

柴金玲;张高勇;李干佐;李英;徐桂英;马忠娟   

  1. 山东大学胶体与界面化学教育部重点实验室.济南(250100);中国日用化学工业 研究院
  • 发布日期:2001-12-15

Adsorption kinetics of cetyltrimethylammonium bromide at the air/water interface

Chai Jinling;Zhang Gaoyong;Li Ganzuo;Li Ying;Xu Guiying;Ma Zhongjuan   

  1. Shandong Univ., College of build mater and light ind, Dept of ma. Jinan(250100)
  • Published:2001-12-15

Maximum bubble pressure method (MBPM) was used to determine the dynamic surface tension of aqueous solution of cetyltrimethylamonium bromide (CTAB). Adsorption kinetics of CTAB at the air/water interface has been studied. Effects of temperature, concentration of CTAB, additives on the adsorption kinetics were also investigated. The results show that at beginning, the adsorption process is controlled by a diffusion step; whereeas toward the end, it changes to an activation mechanism with an adsorption barrier of between 4 and 10 kJ.mol^-^1. It seems that this burrier does not depend on the temperature and additives. Additives influence diffusion process significantly.

Key words: ADSORPTION, KINETIC STUDY, SURFACE TENSION

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