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有机化学
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有机化学 ›› 2011, Vol. 31 ›› Issue (11): 1799-1810. 上一篇    下一篇

综述与进展

三芳胺合成的研究进展

刘涛平，孙杰，李瑞，陶晓春*   

  1. (1华东理工大学化学与分子工程学院 上海 200237)
    (2镇江市海通化工有限公司 镇江 212125)
  • 收稿日期:2011-06-24 修回日期:2011-08-12 发布日期:2011-08-24
  • 通讯作者: 陶晓春 E-mail:xctao@ecust.edu.cn

Recent Progress in the Synthesis of Triarylamine

LIU Tao-Ping, SUN Jie, LI Rui, TAO Xiao-Chun   

  1. (1 School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237)
    (2 Zhenjiang Haitong Chemical Industry Co., Ltd., Zhenjiang 212125)
  • Received:2011-06-24 Revised:2011-08-12 Published:2011-08-24

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被引次数

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三芳胺化合物的合成方法主要有3种: (1)非金属催化的胺化反应|(2)铜催化的Ullmann反应, 包括使用过量铜粉为催化剂的传统的Ullmann反应、使用相转移催化剂的Ullmann反应以及使用配体的post-Ullmann反应|(3)钯催化的Buchwald-Hartwig反应. 该类反应活性的关键是配体的选择, 根据配体结构的不同可分为双膦螯合型配体、单膦配体和非膦配体. 对该类化合物的这几种合成方法的研究进展进行了总结.

关键词: 三芳胺, 研究进展, 合成方法, 钯催化, 铜催化

Three different synthetic methods have been developed for the triarylamine: (1) non-metal catalyzed amination reaction;(2) Ullmann reaction which can be divided to traditional Ullmann reaction using excess copper as catalyst, using phase-transition-catalyst as auxiliary and post-Ullmann reaction using ligand;(3) Buchwald-Hartwig reaction catalyzed by palladium complexes. The key issue for the activity of this reaction is the structure of ligand. There are three types ligand: chelate diphosphine ligand, monophosphine ligand and non-phosphine ligand. This review is focused on the recent progress of the synthesis methods of triarylamine.

Key words: triarylamine, progress, synthetic method, palladium-catalyzed, copper-catalyzed